ANTHROPOGENIC AND GEOGENIC CONTAMINATION DUE TO HEAVY METALS IN THE VAST AREA OF VARI, ATTICA

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Published: Jan 1, 2010
DOI: https://doi.org/10.12681/bgsg.11639
Keywords:
soil contamination heavy metals anthropogenic factors geogenic- lithogenic factors HCA PCA Vari Attica
K.G. Serelis
I.G. Kafkala
K. Parpodis
S. Lazaris
Abstract

The purpose of this work was to investigate the soil heavy metal contamination of the area between Koropi and Vari, in Attica, Greece and to determine their anthropogenic or/and geogenic-lithogenic origin. Soil samples were taken from two different depths of 23 uncultivated sampling sites. Determined heavy-metal concentrations ranged widely; mean values in several sites were elevated and much higher than the soil grand mean worldwide. The higher Co and Ni contamination was found in the lower soil depth (10-25cm), while for Cd, Zn, and Pb in the upper depth (0-10cm). These results, in connection with the performed Hierarchical Cluster Analysis and Principal Component Analysis, indicate that there are two contamination sources. The first, concerning Co-Ni, is a geogenic-lithogenic source and the second, concerning Zn-Cd and Pb, is considered as an anthropogenic source. Since in the study area there is no evidence of an existing anthropogenic source (e.g. an industry) and the parent material does not confirm and give reason for the elevated Zn, Cd and Pb contents, it could be concluded that this contamination was due to ancient metallurgical activities in the area.

Article Details
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  • Geochemistry and Ore Deposit Geology
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References
Allison, L. E. and Moodie, C. D., 1965. Carbonate. In: CA Black (ed.) Methods of Soil Analysis, part 2.
Agronomy 9: 1379–1400. Am Soc of Agron, Madison, Wisconsin, USA.
Alloway B. J., 1995. Heavy metals in soils, 2nd Edition, Springer 1995, pp. 384.
Bouyoukos, G.J., 1951. A recalibration of the hydrometer method of making mechanical analysis of soils.
Agron. J. 43: 434-437.
Burt, R., Wilson, M., Mays, M.D., Lee, C.W., 2003. Major and trace elements of selected pedons in the
USA. J. Environ. Qual. 32:2109-2121 (2003).
Clayton, P.M. and Tiller, K.G., 1979. A Chemical Method for the Determination of the Heavy Metal Content
of Soils in Environmental Studies. In: Paper No. 41, CSIRO Australia, Melbourne Div. Soils
Tech. (1979), pp. 1–17.
Dudka, S., Adriano, D.C., 1997. Environmental impacts of metal ore mining and processing: a review.
Journal of Environmental Quality 26: 590-602.
Fytianos, K., Katsianis, G., Triantafyllou, P., Zachariadis, G., 2001. Accumulation of heavy metals in
vegetables grown in an industrial area in relation to soil. Bull. Environ. Contanim. Toxicol. 67: 423-
Girard, M-C., Walter, C., Rémy, J-C., Berthelin, J., Morel, J-L., 2005. Sols et environnement, Éditions
Dunod, Paris, 2005.
Godin, P.M., Feinberg, M. H., Ducauze, C. J., 1985. Modelling of soil contamination by airborne lead and
cadmium around several emission sources. Environmental Pollution Series B, Chemical and Physical,
:2 (1985), pp. 97-114.
I.G.M.E. KOROPI-VARI sheet 2004 Geological map 1:50.000. Department of geological maps of IGME,
Athens, Greece.
XLIII, No 5 – 2396
Imperato, M., Adamo, P., Naimo, D., Arienzo, M., Stanzione, D., Violante, P., 2003. Spatial distribution
of heavy metals in urban soils of Naples city (Italy). Environmental Pollution 124 (2003) 247–256.
Kabata-Pendias, A, and Pendias, H., 2001.Trace elements in soils and plants, 3rd Edition, CRC Press LLC,
pp. 413.
Kakavoyianni, O., 2003. A EH I Metallurgy Workshop of Silver in Lambrika, Attica (Koropi). Archaeology
& Arts 94, 45-48 (in Greek with abstract in English).
Kribek, B., Majer, V., Veselovsky, F., Nyambe, I., 2010. Discrimination of lithogenic and anthropogenic
sources of metals and sulphur in soils of the central-northern part of the Zambian Copperbelt Mining
District: A topsoil vs. subsurface soil concept. doi: 10.1016/j.gexplo.2009.12.005.
Lazaris, Sp., 2008. Determination of heavy-metal contamination sources in soils of Koropi-Vari area, Attica.
Master thesis, Agricultural University of Athens (in greek).
Lin, C., Negev, I., Eshel, G., Banin, A., 2008. In situ accumulation of copper, chromium, nickel, and zinc
in soils used for long-term waste water reclamation. Journal of Environmental Quality 37: 1477-
Mousoulos, P., 1976. Metallurgy of Pb. National Engineering School, Athens 1976 (in greek), pp. 125.
Nelson, D.W. and Sommers, L.E., 1982. Total carbon, organic carbon, and organic matter, pp. 539-579.
IN: A. L. Page, R. H. Miller, and D. R. Keeney (eds.) Methods of Soil Analysis Part 2, Chemical and
Microbiological Properties Soil Science Society of American, Inc., Madison, WI.
Quevauviller, Ph., Lachica, M., Barahona E., Rauret G., Ure, A., Gomez, A., Muntau, H., 1996. Interlaboratory
comparison of EDTA and DTPA procedures prior to certification of extractable trace elements
in calcareous soil. The Science of the Total Environment 178 (1996) 127-132.
Quevauviller, Ph., Lachica, M., Barahona, E., Gomez, A., Rauret, G., Ure, A., Muntau. H.,1998. Certified
reference material for the quality control of EDTA- and DTPA-extractable trace metal contents
in calcareous soil (CRM 600). Fresenius J Anal Chem (1998) 360 : 505–511.
Selinus, O., Alloway, B., Centeno, J. A., Finkelman, R. B., Fuge, R., Lindh, R., Smedley, P., 2005. Medical
Geology, Elsevier Academic Press, 2005, pp. 812.
Shakeri, A., Moore, F. and Modabberi, S., 2009. Heavy Metal Contamination and Distribution in the Shiraz
Industrial Complex Zone Soil, South Shiraz, Iran. World Applied Sciences Journal 6 (3): 413-
Singh, A., Sharma, R.K., Agrawal, M., Marshall, F.M., 2010. Health risk assessment of heavy metals via
dietary intake of foodstuffs from the wastewater irrigated site of a dry tropical area of India. Food and
Chemical Toxicology 48: 611-619.
Van Hullebusch, E.D., Gieteling, J., Zhang, M., Zandvoort, M.H., Van Daele, W., Defrancq, J., Lens,
P.N.L., 2006. Cobalt sorption onto anaerobic granular sludge: Isotherm and spatial localization analysis.
Journal of Biotechnology 121: 227-240.
Wong, S.C., Li, X.D., Zhang, G., Qi, S.H., Min, Y.S., 2002. Heavy metals in agricultural soils of the Pearl
River Delta, South China. Environmental Pollution 119: 33-44.
Zhuang, P., McBride, M.B., Xia, H., Li, N., Li, Z., 2009. Health risk from heavy metals via consumption
of food crops in the visinity of Dabaoshan mine, South China. The Science of the Total Environment
: 1551-1561.
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