COMPARATIVE STABLE ISOTOPES STUDY OF THE MAGNESITE DEPOSITS OF GREECE


E. Gartzos
Abstract

The magnesite deposits of North Evia, Lesvos and Chalkidiki, which are hosted by Alpine type ultramafic rocks, have been studied from an isotopie point of view and are compared with similar magnesite deposits occurring in other countries of central-southeastern Europe and Turkey. Magnesites from N. Evia, Lesvos and Chalkidiki have similar isotopie compositions. They have 513CPDB values ranging from -8.6 %o to -14.8 %o and 518OSMOW values ranging from 24.0 %oto 30.1 %o, which indicate a rather similar formation process for all three areas. The studied Greek magnesite deposits have similar isotopie compositions with vein and stockwork type magnesite deposits from: Turkey (Koyakci Tepe, vein and stockwork types; Helvacibaba, stockwork type), Poland (vein type), and Former Yugoslavia (vein type). There is strong isotopie evidence that meteoric water is involved in the formation of the stockwork and vein type magnesite deposits of all four countries, including Greece. There is also isotopie evidence for the organic origin of carbon participating in the carbonates (magnesites) of these deposits.

Article Details
  • Section
  • Geochemistry
Downloads
Download data is not yet available.
References
Barnes I. & O'Neil J.R. 1971. Calcium magnesium carbonate solid solution from holocene conglomerate cements and travertines in the Coast Ranges of California. G.C.A., 35, 699-718.
Barnes I., O'Neil J.R., Rapp J. & White D. 1973. Silica carbonate alteration of serpentine: wall rock alteration in mercury deposits of the Coast Ranges of California. Econ. Geol., 68, 388-398.
Barnes I., Leonis C. & Papastamataki A. 1986. Stable isotope tracing of the origin of carbon dioxide discharges in Greece. Proa Int. Symp. Underground water tracing, Athens, 1, 29-43.
Burgath K., Grissemann C, Johannes W., Jung D., Knolke H., Cockel F., Makris J., Mohr M., Mussalam K. & Raschka H. 1981. On the genesis of magnesite deposits in Northern Greece. Proc. Int. Symp. of Unesco, Project N° 169 (Metallogeny of mafic and ultramafic complexes), 3, 226-239.
Capedri S. & Rossi A. 1973. Conditions governing the formation of ophicalcites and listwanites (Central Evia, Greece). Bull. Geol. Soc. of Greece, 10/2, 278-297.
Capedri S. 1974. Genesis and evolution of a typical Alpine-type peridotite mass under deep-seated conditions (Central Evia, Greece). Boll. Soc. Geol. lt., 93, 81-114.
Craig H. 1963. The isotopie geochemistry of water and carbon in geothermal areas. In: Tongiorgi E. (ed.), Nuclear geology in geothermal areas. Consiglio Nazionale delle Ricerche, Laboratorio de Geologia Nucleare, Pisa, Italy, 17-53.
Dabitzias S. 1980. Petrology and genesis of the Vavdos cryptocrystalline magnesite deposits, Chalkidiki peninsula, Northern Greece. Econ. Geol., 75,1138-1151.
Dabitzias S. 1981. Additional evidence and a synopsis on the origin of the magnesite deposits in the Vavdos district, Northern Greece. Proc. Int. Symp. of Unesco, project N° 169 (Metallogeny of mafic and ultramafic complexes), 3, 269-283.
Emrich K., Ehhalt D.H., & Vogel J.C. 1970. Carbon isotope fractionation during the precipitation of calcium carbonate. Earth Planet. Sci. Letters, 8, 363-371.
Fallick Α., Mich M. & Russell M. 1991. A stable Isotope Study of the magnesite Deposits associated with the Alpine-Type Ultramafic rocks of Yugoslavia. Econ. Geology, 86, 847-861.
Friedman I. & O'Neil JR. 1977. Data of geochemistry, 6th ed. Chapter KK: Compilation of stable isotope Fractionation factors of Geochemical interest. Geol. Surv. Prof. Paper, 440-KK.
Gartzos E. 1986. On the genesis of cryptocrystalline magnesite deposits in the ultramafic rocks of N. Evia. Ph.D. thesis, ΕΤΗ Zurich, 195 p.
Gartzos E. 1990. Carbon and oxygen isotope constraints on the origin of magnesite deposits, N. Evia (Greece). S.M.P.M., 70, 67-72.
Gartzos E. & Stamatis G. 1996. Genesis of the thermal springs of Sperchios graben, Greece. N. Jb. Geol. Paleont., H2, 91-115.
Gartzos E., Migiros G., Serelis K. & Parhahdis I. 1994. The ultramafic rocks of Evia - E. Thessaly and the hosted chromitites. 7th Int. Congress Geol. Soc. Greece, XXX/3, 137-153.
Gat J.R. & Carmi I. 1970. Evolution of the isotopie composition of atmospheric waters in the Mediterranean Sea area. J. Geophys. Res. 75, 3039-3048.
Guernet C. 1971. Etudes géologiques en Eubee et dans les regions voisins (Grece). Ph.D. thesis, Univ. Paris, 395 p.
Illic M. 1968. Problems of the genesis and genetic classification of magnesite deposits. Geologica Carpathica, XIX, 1.
Irwin H., Curtis C. & Coleman M. 1977. Isotopie evidence for source of diagetic carbonates formed during burial of organic-rich sediments. Nature, 269, 209-213.
Jedrysek M. & Halas S. 1990. The origin of magnesite deposits from the Polish Foresudetic Block ophiolites: preliminary 513C and δ180 investigations. Terra Nova, 2,154-159.
Le Pichon X. & Angelier J. 1979. The Hellenic arc and trench system. Tectonophysics, 60,1-42.
O'Neil J. R. & Barnes I. 1971. Carbon and oxygen isotopie compositions in some fresh water carbonates associated with ultramafic rocks and serpentinites, W. USA. G.S.A., 35, 687-697.
Papastamataki A. & Leonis K. 1982. Reports on geochemical exploration of geothermal fields: (I) Area of Lesvos, (II) Area of Platistomo, (III) Area of Edipsos, (IV) Area of Loutraki - Sousaki. I.G.M.E., Athens.
Petrascheck W.E. 1964. Weitere Erkenntnisse über die Bildung der Lagerstatten des dichten Magnesits und des Meerschaums. Randex-Rdsch, Radenthein, 2, 103-108.
Pohl W. 1990. Genesis of magnesite deposits - models and trends. Geologische Rundschau, 79/2, 291-299.
Serelis K. & Gartzos E. 1994. The ultramafic rocks of Lesvos. 7th Int. Cong. Geol. Soc. Greece, XXX/3,113-124.
Zedef V., Russell M., Fallick A. & Hall A. 2000. Genesis of Vein Stockwork and Sedimentary Magnesite and Hydromagnesite Deposoits in the Ultramafic Terranee of Southwestern Turkey: A Stable Isotope Study. Econ. Geology, 95, 429-446.