THE BALKAN MOUNTAINS PALEOZOIC GOLD DEPOSITS


V. Mladenova
T. Kerestedjian
D. Dimitrova
Abstract

A number of Paleozoic gold deposits are situated in the Hercynian terrains of the Balkan Mountain. On Bulgarian territory Govezhda and Svishti Plaz deposits are the most important ones. Neresnitza, Blagoev-Ka nen and Osanitza deposits are located in the Serbian part of the Balkan Mountain. All these deposits are hosted in the Pre-Alpine basement of the Balkanide zone. The orehosting structures are veins, lenses and mineralized fissures related to tension and shear faults. The structural characteristics of the ores are an evidence for tectonic control and tectonic activity during the ore deposition. All stages of ore deposition were accompanied by strong fracturing of already deposited minerals and subsequent precipitation of next portion. The economically important mineral in all these deposits is the native gold, with variable Ag contents. In the two Bulgarian deposits the main ore minerals are arsenopyrite and pyrite. Arsenopyrite is not reported for Serbian deposits, but scheelite is a main mineral there instead. Based on mineral associations, three possible genetic concepts of Au deposition could be expressed. 1) The gold is genetically associated with arsenopyrite and pyrite from stage 1 (Fe-As- Au+W). It is primarily deposited as invisible gold in these minerals. During the next stage of sulfide deposition driven by induced heating, it is remobilized and redeposited in cracks, formed during the cataclastic events of this stage. 2) The gold is genetically connected to the stage 2 (Pb-Zn-Cu-Ag- Au). 3) Dual generation of gold related to both stages 1 and 2. All Balkan Paleozoic gold deposits show lots of similarities to mesothermal gold deposits in shear zones in Archaean greenschists terrains in Canada, Western Australia and Africa, as well as to Hercynian gold deposits in France and Portugal. The similarity especially concerns their connection to granodiohtic magmatism, the mineral parageneses and the gold occurrence and its associations. Despite that the mining in the Balkan gold deposits is already closed, they still have nonexplored and non-operated reserves

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  • Economic Geology
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References
Alpers, C. N., Blowes, D. W., Nordstrom, D. K., and Jambor, J. L, 1994. Secondary minerals and acid mine water chemistry, In: The environmental geochemistry of sulfide mine-wastes, Mineralog. Assoc. Canada, Short Course Handbook, 22, 247-270.
Amov, B., Arnaudov, V., Pavlova, M., Dragov, P., Baldjieva, T., and Evstatieva, S., 1981. Lead isotope data on the Paleozoic granitoids and ore mineralizations from the Western Balkan Mountains and the Tran District (West Bulgaria). I. Isotopie ratios and geochronology, Geol. Bale, 11,2, 3-26.
Ashley, P. M., Creagh, C. J., and Ryan, C. G., 2000. Invisible gold in ore and mineral concentrates from the Hillgrove gold-antimony deposits, NSW Australia, Mineral. Deposita, 35, 285-301.
Bouchot, V., Gros, Y., and Bonnemaison, M., 1989. Structural controls on the auriferous shear zones of the Saint Yrieix District, Massif Central, France: evidence from the Le Bourneix and Laurieras Gold deposit, Econ. Geol., 84, 1315-1327.
Cathelineau, M., Boiron, M-C, Holliger, P., Marion, P., and Denis, M., 1989. Gold in arsenopyrites: crystal chemistry, location and state, physical and chemical condition of deposition, Econ. Geol., Monogr. 6, 328- 341.
Cassidy, K. F., Groves, D. I., and McNaughton, N. J. 1998. Late-Archean granitoid-hosted lode-gold deposits, Yilgarn Craton, Western Australia: deposit characteristic, crustal architecture and implications for ore genesis, Ore Geol. Rev., 13, 65-102.
Cheshitev, G., Milanova, V., Sapunov, I., and Tchoumatchenco. P., 1995. Explanatory note to the geological map of Bulgaria on scale 1:100000, Teteven map sheet, 94 p., (in Bulgarian).
Cook, N. J., and Chryssoulis, S. L, 1990. Concentrations of "invisible gold" in the common sulfides, Can. Mineral., 28,1-16.
Foster, R. P., 1990. Gold mineralization: recent advances in predictive metallogeny, Terra Review, 215-225.
Groves, D. I., Goldfarb, R. J., Gebre-Mariam, M., Hagemann, S. G., and Robert, F., 1998. Orogenic gold deposits, a proposed classific ation in the context of their crustal distribution and relationship to other gold deposit types, Ore Geol. Rev., 13, 7-27.
Haydoutov, I., 1991. The Thracian Hercynian suture and the related magmatism, Geotect., Tectonophys. and Geodynam., 23, 3-25 (in Bulgarian).
Ivanov, J., 2002. Tectonics of Bulgaria, Sofia University Press, (in press).
Ivanov, Z., Kolceva, K., Moskovski, St., and Dimov, D., 1987. Des particularités et du caractère de la "formation diabaso-phyllitoide", Rev. Bui. Geol. Soc, 48, 2, 1-24 (in Bulgarian).
Jambor, J. L., Blowes, D. W., and Ptacek, C. J., 2000. Mineralogy of mine wastes and strategies for remediation, In: EMU Notes in Mineralogy, 2, Ch. 7, 255-290.
Jankovic, S., 1982. Yugoslavia, In: Dunnina et al. Eds., Mineral deposits of Europe, 1982, 2, 406pp.
Kalaidjiev, S., Stoyanov, S., Tzvetkov, T., and Stoyanov, I., 1989. New data on the distribution of hydrothermal mineralizations in Govejda ore field, In: Geology and Ore Deposits of North-West Bulgaria, Sofia, Technika, 108-114 (in Bulgarian).
Kamenov, B. K., Quadt, A. v, and Peytcheva, J., 2002. New insight into petrology, geochemistry and dating of the Vejen pluton, Bulgaria, Geochem., Mineral. Petrol., 39, 3-25.
Kujkin, S. S., and Milanov, L. Β., 1970. Über dem Geologischenbau von einem Teil der Zlatishka Stara planina, Rev. Bulg. Geol. Soc, 31, 1, 120-126 (in Bulgarian).
Kuikin, S., Staikova, M., and Hristov, S. 1972. Über die Gold-Sulfid Vererzung in Zlatica-Balkan, Bull. Geol. Inst, 21, 55-68 (in Bulgarian).
Marmont, S., and Corfu, F., 1989. Timing of gold introduction in the late Archaean tectonic framework of the Canadian Shield: Evidence from U-Pb Zircon Geochronology of the Abitibi Subprovince, Econ. Geol. Monogr.,6, 101-111.
Milev, V., Stanev, V., and I 'anov, V., 1996. The mined ore in Bulgaria in the period 1878-1995, Statistical reference book, Sofia, Zemja, 196pp, (in Bulgarian).
Mladenova, V., and Kerestedjian, T., 2002. The Svishti Plaz gold deposit, Central Balkan Mountain, Bulgaria, Geochem. Mineral. Petrol.. 39, 53-65.
Mladenova, V., Kerestedjian, T., and Dimitrova D., 2001. Ag-Cu-Pb-Bi mineralization from the Svishti Plaz gold deposit, Central Balkan Mountain, Bulgaria, Geochem., Mineral. Petrol, 38, 55-66.
Mladenova, V., Kerestedjian, T., and Dimitrova, D., 2003. The Govezhda gold deposit, Western Balkan Mountains, Bulgaria, Geochem. Mineral. Petrol., 40, 109-121.
Möller, P., 1994. Accumulation of gold on natural sulfides: the electrochemical function of arsenic in nature, Geol. Jb., D100, 639-660.
Möller, P., 1995. Accumu ation of gold by electrochemical processes, In: Prehistorical gold in Europe, G. Morteani & J. P. Northover (eds.), 145-157.
Möller, P., and Kersten, G., 1994. Electrochemical accumulation of visible gold on pyrite and arsenopyrite surfaces, Miner. Deposita, 29, 404-413.
Mueller, A. G., Harris, L. B., and Lungan, Α., 1988. Structural control of greenstone-hosted gold mineralization by transcurrent shearing: a new interpretation of the Kalgoorlie Mining District, Western Australia, Ore Geol. Rev., 3, 359-387.
Mumin, A. H., Fleet, M. E., and Chryssoulis, S. L, 1994. Gold mineralization in As-rich mesothermal gold ores of the Bogosu-Prestea mining district of the Ashanti Gold Belt, Ghana: Remobilization of "invisible" gold, Mineral. Deposita, 29, 445-460.
Nikolaev, G., Tonev, I., 1961. Geological setting of vicinity of Kopilovci village and the mineralization of the goldquartz- sulfide veins, Ann. Univ. Mining Geol., Sofia, 7, 2, 23-36 (in Bulgarian).
Oberthür, T., Blenkinsop, T. G., Hein, U. F., Höppner, M., Höhndorf, Α., and Weiser, T. W., 2000. Gold mineralization in the Mazowe area, Harare-Bindura-Shamva greenstone belt, Zimbabwe: II. Genetic relationships deduced from mineralogical, fluid inclusion and stable isotope studies, and the Sm-Nd isotopie composition of scheelites, Mineral. Deposita, 35, 138-156.
Oberthür, T., Weiser, T., Amanor, J. Α., and Chryssoulis, S. L, 1997. Mineralogical sitting and distribution of gold in quartz veins and sulfide ores of the Ashanti mine and other deposits in the Ashanti mine and other deposits in the Ashanti belt of Ghana: genetic implications, Mineral. Deposita, 32, 2-15.
Parvanov, I., and Mateev, S., 1980. Report on exploration results of Svishti Plaz gold deposit in 1975-1979 with mineral reserves calculation, Unpubl., NationalGeofund, (in Bulgarian).
Petrov, H., 1981. Report on the exploration in 1974-1980 in Brezov Rat, Cherna Reka, Izvora and Debeli Rat subsections of the Central part of the Govezhda gold deposit, Mihaylovgrad district, Geofund Comm. Geol.,Unpubl., 1-1030 (in Bulgarian).
Robert, F., and Brown, A. C, 1986. Archean gold-bearing quartz veins at the Sigma mine, Abitibi greenstone belt, Quebec: Part I. Geologic relations and formation of the vein system, Econ. Geol., 81, 578-592.
Touray, J.-C, Marcoux, E., Hubert, P., and Proust D., 1989. Hydrothermal processes and ore-forming fluids in the Le Bourneix gold deposit, Central France, Econ. Geol., 84,1328-1339.
Wu, X., Delbove, F., and Touray, J. C, 1990. Condition of formation of gold bearing arsenopyrite: a comparison of synthetic crystals wi*h samples from Le Chatelet gold deposit, Creuse, France, Mineral. Deposita, 25, 8- 12.
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