GEOCHEMICAL- MINERALOGICAL AND METALLOGENETICAL ASPECTS CONCERNING THE ORIGIN OF SEDIMENTS FROM LEG. 22 D.S.D.P DRILLED SITES 212 AND 213 IN EASTERN INDIAN OCEAN


Published: Jan 1, 2007
Keywords:
Deep sea sediments and clays Fe-Mn oxides authigenic minerals
C. T. Papavassiliou
Abstract

Basic mineralogical and geochemical data, are presented for sediment core samples from Deep Sea Drilling Project(D.S.D.P) boreholes .Sites 212 and 213 respectively, from the eastern Indian Ocean. In both Sites the Fe-Mn oxides are abundant controlling a numerous suite of trace elements. In Site 212 the Fe-Mn oxides are more abundant in the upper part of the borehole having mainly a diagenetic or hydrogenous origin, whilst in Site 213 these oxides are more abundant in the lower part having mainly a hydrothermal origin. In both Sites clay minerals are consisting mostly of the expandable mixed layered smectite/illite. The geochemical data shows that in both Sites the majority of the sediments have the characteristics of typical deep sea clay being both of detrital and authigenic origin. In Site 212 these clays with considerable amount of palygorskite and the zeolite clinoptilolite, both of authigenic origin, opaline silica, biogenous CaCOj ,the Fe-Mn oxides and some other detrital minerals together control the bulk chemical composition of the sediments. In Site 213 the clays with large amounts of Fe-Mn oxides and considerable amounts of the zeolite Phillipsite and Palygorskite in small amounts and some other detrital minerals, control the chemical composition of the sediments. The increase in the Ti/Al and Mg/Al ratios with depth in both Sites implies a volcanoclastic input in the bottom sediments probably from the underlying basaltic basement

Article Details
  • Section
  • Mineralogy-Petrology-Geochemistry-Economic Geology
Downloads
Download data is not yet available.
References
Bostrom, K., Joensuu, O., and Brohm, I., 1974. Plankton-its chemical composition and its significance as a source of pelagic sediments, Chem.Geol., 14, 255-271.
Bostrom, K, Joensuu, O, Valdes, S, Charm, W, and Glaccum, R., 1976. Geochemistry and origin of East Pacific sediments sampled during DSDP leg 34, Initial Reports of the Deep Sea Drilling Project, Volume XXXIV, Washington (U .S. Government Printing Office), 559-574pp.
Calvert , S.E., and Price, N.B., 1970. Minor metal contents of recent organic-rich sediments off South West Africa Nature, 227, 593-595.
Calvert, S.E., 1976. The mineralogy and geochemistry of near-shore sediments. In J.P. Riley and R. Chester (eds). Chemical Oceanography, London Academic Press, 6, 187-280.
Chester, R., 1965. Elemental geochemistry of marine sediments. In J.P. Riley and G. Shirrow (eds), Chemical Oceanography, London Academic Press, 2, 23-80.
Chester, R., and Aston, R.S., 1976. The geochemistry of Deep Sea Sediments. In J.P. Riley and R. Chester (eds). Chemical Oceanography, London Academic Press, vol. 6, 281-390pp.
Chester, R., 1990. Marine Geochemistry, Published by Unwin Hyman Ltd. London , 700pp.
Cosgrove, M.E., and Papavasiliou, CT., 1979. Clinoptilolite in DSDP sediments of the Indian Ocean (Site 223, Leg 23): Its stability conditions and estimation of its free energy, Marine.Geol, 19,77-84.
Couture, R.A. 1977. Composition and origin of palygorskite-rich and montmorillonite- rich zeolite-containing sediments from the Pacific Ocean, Chem.Geol., 19, 113-130.
Cronan, D.S., 1969. Inter-element association in some pelagic deposits, Chem. Geol, 5, 99-106.
Donnely, T.W., and Wallace, J.L., 1976. Major and minor element chemistry of Antarctic clayrich sediments: Sites 322, 323, and 325, DSDP Leg.35. In Initial Reports of Deep Sea Drilling Project, vol. 35, Washington (U.S.Government Printing Office), 427-446pp.
Goldshmidt, V.M., 1954. Geochemistry, Oxford University Press, London, 730pp.
Griffin, J., Windom, H., and Goldberg, E., 1968. The distribution of clay minerals in the World Ocean, Deep Sea Reshearch, 15, 433-459.
Gromet, L.P., Dymek, R.F., Haskin, L.A., and Korotev, R.L., 1984. The "North American shale composite": its compilation, major and trace element characteristics, Geochim. Cosmochim. Acta, 48, 2469- 2482.
Hart, R.A., 1976. Chemical variance in deep ocean basalts, Initial Reports of Deep Sea Drilling Project, vol. 34, Washington (U.S.Government Printing Office), 301-339pp.
Hirst, M.D., 1974. Geochemistry of sediments from eleven Black Sea cores. In E.T. Degens and DA. Ross (eds), The Black Sea geology, chemistry and Biology, Amer. Assoc.Petrol.Geol. Mem, 20, 430-455pp.
Kolla, V., 1974.Mineralogical data from Sites 211, 212, 213, 214, 215 of Deep Sea Drilling Project Leg 22, and origin of non-carbonate sediments in the equatorial Indian Ocean, Initial Reports of Deep Sea Drilling Project, vol. 22, Washington (U.S.Government Printing Office), 489-501.
Kolla, V., Henderson, L., and Biscaye, P.E., 1976. Clay mineralogy and sedimentation in the Western Indian Ocean, Deep Sea Research, 23, 949-961.
Kolla,V., Kostecki, J.A., and Robinson, F., 1981. Sediments of region of clay minerals and quartz in surface sediments of the Arabian Sea, Journ.Sedim.Petrol, 51, 563-569.
Krauskopf, K.B., 1967. Introduction to Geochemistry,McGraw-Hi, New York, N.Y. 721pp.
Matti, J.C., Zemmels, I., and Cook, H.E., 1974. X-ray mineralogy data north-eastern part of the Indian Ocean, Leg 22, Deep Sea Drilling Project. In Initial Reports of Deep Sea Drilling Project, vol. 22, Washington (U.S.Government Printing Office), 693-710pp.
Owen, R.M., and Zimmerman, A.R.B., 1991. Geochemistry of Broken Ridge Sediments. In Proceedings of the Ocean Drilling Program, Scientific Results, vol. 121, 437-445pp.
Papavasiliou, C.T., 1979. The geochemistry and mineralogy of some N.W. Indian Ocean cores (Sites 222 and 223, LEG.23, D.S.D.P., Unbubl. PhD thesis, University of Southampton.
Pimm, A.C., 1974. Sedimentology and history of the north-eastern Indian Ocean from late Cretaceous to Recent. In Initial Reports of Deep Sea Drilling Project, vol. 22, Washington (U.S.Government Printing Office) 717-730pp.
Sclater, J.G., von der Borch, C.C., and Veevers, J.J., 1974. Regional synthesis of the deep sea drilling results from Leg.22 in the eastern Indian Ocean. In Initial Reports of Deep Sea Drilling Project, vol. 22, Washington (U.S.Government Printing Office).
Subbaro, K.V., Kempe, D.R.C., Reddy, G.R., and Hekinian, 1979. Review of the geochemistry of Indian and other oceanic rocks. In Ahrens (ed.), Origin and Distribution of Elements: Second Symposium, Physics and Chemistry of the Earth, vol. II, Pergamon Press, Oxford, 367-399pp.
Taylor, S.R, and McLennan, S.M., 1985. The continental crust: its composition and evolution. An examination of the geochemical record preserved in sedimentary rocks, Geoscience Texts, Blackwell Scientific Publications, Oxford, 9-56pp.
Turekian, K.K., and Wedepohl, K.H., 1961. Distribution of the elements in some major units of the earth's crust, Bull.Geol.Soc.Amer. ,72, 175-192.
Turekian, K.K., 1964. The marine geochemistry of Strontium, Geochim. Cosmochim. Acta, 28 1479-1496.
Van der Weijden. C„ Reichart, G.J , and Van Os, B., 2006. Sedimentary trace element records over the last 200 kyr from within and below the northern Arabian Sea oxygen minimum zone, Marine Geology, 231, 69-88
Von der Borch, Sclater, J.G., et al., 1974. Site Reports. In Initial Reports of Deep Sea Drilling Project, vol. 22, Washington (U.S.Gove 1 ment Printing Office).
Weser, O.E., 1974. Sedimentological aspects of strata encountered on Leg.23 in the northern Arabian Sea. In Initial Reports of Deep Sea Drilling Project, vol. 23, Washington (U.S. Government Printing Office), 503-519pp.