REPLACEMENT OF Ti02 PIGMENT BY CaC03 FROM CEFALONIA IN EMULSION PAINTS


K. Kalafati
G. E. Christidis
Résumé

The purpose of this work is to show that calcium carbonate from the chalky limestone deposits of Minies in Kefalonia, exploited by IONIAN KALK S.A., is a suitable raw material for paint industry and especially in emulsion (water based) paints. The deposit is characterized by a high calcium carbonate content (>99 %), high whiteness and low yellowness, by negligible content of heavy metals and low contents of MgO (<0.15 %), Si02 (<0.05 %) andFe203 (<0.01 %). This research was based on determination of the optical and mechanical properties of the emulsion white water based paints, which included calcium carbonate from the Kefalonia limestone deposits. The calcium carbonate replaced Ti02 pigment in various proportions. It is concluded that this product can be utilized not only as inert filler and extender but may have more functional application acting simultaneously as pigment. Replacement of TiO2 pigment by calcium carbonate may reach 50% without deteriorating the optical and mechanical properties significantly. Hence calcium carbonate from this deposit offers excellent optical properties to paints, reduces sufficiently their production cost and replaces a great part of the proportion of titanium dioxide, which is currently used as white pigment.

Article Details
  • Rubrique
  • Mineralogy-Petrology-Geochemistry-Economic Geology
Téléchargements
Les données relatives au téléchargement ne sont pas encore disponibles.
Références
Bergman, H., 1964. Geological Map of Greece, Kefalonia Sheet, scale 1:50,000.
Billmeyer, F.W., and Saltzman, M., 1981 Principles of color technology, 2nd edition. l-23pp., Wiley Interscience, New York.
British Standards Institution BS3900, 1986. Parts D8, D9 and DIO. Determination of colour and colour difference: principles, measurement and calculation.
Carr, D.D., Rooney, L.F., and Freas, R.C., 1994. Limestone and dolomite. In D.D. Carr (ed.), Industrial Minerals and Rocks, AIMME, 605-609pp.
Christidis, G., Makri, P., and Perdikatsis, V., 2004. Influence of grinding on the colour properties of talc, bentonite and calcite white fillers, Clay Minerals, 39, 163-175.
Christidis, G.E., Sakellariou, N., Repouskou, E., and Marcopoulos, Th., 2004. Influence of organic matter and iron oxides on the colour properties of a micritic limestone from Kefalonia, Bull. Geol. Soc. Greece, 36, 72-79.
Christidis, G., and Scott, P.W., 1997. Origin and colour properties of white bentonites: A case study from the Aegean Islands of Milos and Kimolos, Greece, Miner. Deposita, 32, 271-279.
Naydowski, C, Hess, P., Strauch, D., Kuhlmann, R., and Rohleder, J., 2001. Calcium carbonate and its industrial applications. In F.W. Tegethoff (ed.), Calcium Carbonate. From the Cretaceous Period into the 21s' Century, Birkhäuser Verlag, Basel, 197-311pp.
Power, T., 1985. Limestone specifications. Limiting constraints on the market, Industrial
Minerals, 217, 65-91.
Scott, P.W., and Dunham, A.C., 1984. Problems in the evaluation of limestone for diverse markets, 6th Industrial Minerals International Congress, Toronto, Metal Bulletin, London, 1-21.
Articles les plus lus par le même auteur ou la même autrice