Mineralogical and geochemical study of the Kirki mining wastes, Evros region, Greece -determination of the environmental impact by toxic and heavy metals

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Publiée : Ιαν 1, 2007
DOI : https://doi.org/10.12681/bgsg.16886
Kostas Arikas
Mineralogisch-Petrographisches Institut, Universität Hamburg
Résumé

Mining activity at the Kirki ore deposit has occurred over short periods, from 1974 to 1980 and 1990 to 1997. The mining wastes at the cracked tailing ponds and at other on-site locations of the plant, together with the remains of the mining concentrates, the piles of the unprocessed ore and the large number of destroyed and weathered barrels of chemical reagents, including sodium cyanide, are a great risk to public health. All these wastes are exposed to rain-water and constitute a permanent source of toxic metals and other materials, which are transported by the adjacent small river of Erini, contaminating the hydrologie system of the whole area including the city of Alexandroupolis. For example, the concentrations of toxic metals such as Pb, Cu, Zn, As and Cd in the clay fraction of the river sediments is 2100, 300, 50, 100 and 660 times, respectively, above the natural background concentrations.

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  • Rubrique
  • Natural Environment and Anthropogenic Activities
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Références
Arikas, K., Watzl, V., and Goetz, D., 2004. The environmental pollution from mining activities in Kirki, Alexandroupolis area, Bui. Geo. Soc. Greece, 36, 141-149.
Asfahani, N., Nowak, Α., Arikas, Κ., and Goetz, D., 2005. Die Geochemie der Flotationsrückstände in der Umgebung der stillgelöegten Pb-Zn-Cu-Lagerstätte bei Kirki, Thrakien, Griechenland, Beih. zum Eur. Jour. Miner., 17, 7.
Astaras, T., Oikonomidis, D., Dimopoulos, G., Lambrinos, N., and Filippidis, Α., 1997. Environmental monitoring of the Stratoni/Stratoniki area, Chalkidiki, Greece, using Landsat/TM digital images. In A. Spiteri (ed.), Remote Sensing '96, Rotterdam, Balkema, 145-149pp.
Christofides, G., Soldatos, T., Eleftheriadis, G., and Koroneos, Α., 1998. Chemical and isotopie evidence for source contamination and crustal assimilation in the Hellenic Rhodope plutonic rocks, Acta Vulcano!., 10, 305-318.
Damigos, D. and Kaliampakos, D., 2006. The "battle of gold" under the light of green economics: a case study from Greece, Environ. Geol,. 50, 202-218.
Darlagiannis, D., Vavelidis, M., Arikas, K, Melfos, V., and Goetz, D., 2002. Environmental geochemica; study of the sediments in the Saporema and Filiouris rivers, Sapes-Xylagani area, Rhodope county, Thrace, Greece, Proc. of the 6th Greek Geographical Conference of the Greek Geographical Society, Thessaloniki, 445-452.
De Boorder, Η., Spakman, W., White, S.H., and Wortel, M.J.R., 1998. Late Cenozoic mineralisation, orogenic collapse and slab detachment in the European Alpine Belt, Earth Planet. Sci. Lett., 164, 569-575.
Del Moro, Α., Innocenti, F., Kyriakopoulos, C, Manetti, P., and Papadopoulos P., 1988. Tertiary granitoids from Thrace (Northern Greece): Sr isotopie and petrochemical data, N. Jb. Miner. Abh., 159, 113-135.
Dimou, E., 1993. A correlative mineralogical study of Achia Tarla and St Philippos mineralization, Kirki are (NE Greece), Bui. Geo. Soc. Greece, 28, 37-54.
Driesner, T., and Pintea, I., 1994. Constraints on the conditions of wurtzite formation at the Aghios Philippos Pb-Zn deposit, NE Greece. - Berichte der Deutschen Mineralogischen Gesellschaft, In European Journal Mineralogy, 6, No. 1, 54p.
Finitsi, A.V., Arikas, K., Goetz, D., Darlagiannis, D., Vavelidis, M., and Melfos, V., 2002. Geochemie von Böden und Bachsedimenten im epithermalen Gebiet von Sapes/Perama (Thrakien-Griechenland), Beih. zum Eur. Jour. Miner., 14,43.
Karatasou, E., Vavelidis, M, Melfos, V., Koroneos, Α., and Sklavounos, S., 2005. Heavy metal contamination of the Thermorema stream sediments at the Konos-Sapes district, Thrace, Greece. Proc. of the 2nd Symposium of the Committee of Economic Geology, Mineralogy and Geochemistry of the Geological Society of Greece, Thessaloniki, 133-142.
Kelepertsis, Α., and Bibou, Α., 1991. Heavy metal contamination of soils at old mining sites on Thasos island Greece, Environmental Geochemistry and Health, 13, 23-28.
Kitsopoulos, K., and Pavlidou, E., 2004. Exploitation of gold ores deposits. The press and the local society, environmental protection and concern. The case of Thrace region (Greece), Bui. Geo. Soc. Greece, 36, 350-359.
Michael, C, Constantinides D., Ashworth, K., Perdikatsis, V., and Demetriades, Α., 1989. The Kirki vein polymetallic mineralization, NE Greece, Geologica Rhodopica, 1, 366-373.
Michailidis, K, Filippidis, Α., Vavelidis, M., and Evangelou, E., 1989. Chemical composition of some ore minerals from the St. Philippos (Kirki) polymetallic deposits, Geologica Rhodopica, 1,389-395.
Moelo, Y., Oudin, E., Makovicky, E., Karup-Moller, S., Pillard, F., Bornuat, M., and Evangelou, E., 1985. La kirkiite, PblOBi3As3S19, une nouvelle espece minerale homologue de la jordanite, Bull. Minerai, 108, 667-677.
Mposkos, E.D., and Kostopoulos, D.K., 2001. Diamond, former coesite and supersilicic garnet in metasedimentary rocks from the Greek Rhodope: a new ultrahigh-pressure metamorphic province established, Earth Planet. Sci. Lett., 192, 497-506.
Papadopoulos, P., 1982. Geological map of Greece, Maronia sheet, scale 1:50.000, I.G.M.E., Athens.
Skarpelis, N., 1999. The Agios Filippos ore deposit, Kirki (Western Thrace). A base-metal part of a high-sulfidation epithermal system, Bui. Geo. Soc. Greece, 33, 51-60.
Skarpelis, N., and Triantafyllidis, S., 2004. Environmental impact from supergene alteration and exploitation of a high sulfidation epithermal type mineralisation (Kirki, NE Greece), Transactions of the Institution of Mining and Metallurgy. Section B: Applied Earth Science, 113, 110-116.
Vavelidis, M., Filippidis, Α., Michailidis, K, and Evangelou, E., 1989. The polymetallic ore mineralization of the Kirki area, Alexandroupolis district, Northeastern Greece, Geologica Rhodopica, 1,350-365.
Voudouris, P., Papavasiliou, C, and Melfos, V., 2005. Silver mineralogy of St Philippos deposit (NE Greece) and its relationship to a Te-bearing porphyry-Cu-Mo mineralization, Geochemistry, Mineralogy and Petrology, 43, 155-160.
Watzl, V., 1998. Untersuchung der von Bergbau und Erzaufbereitung verursachten Schwermetallbelastungen entlag des Flusses Erini (Thrakien, Griechenland), Diplomabeit, Mineralogisch-Petrographisches Institut, Universität Hamburg, 110p.