Sustainability analysis for scandium recovery from secondary sources


Published: Nov 28, 2023
Keywords:
Extraction of Scandium Bauxite Residue Rare Earth Elements Life Cycle Assessment Aluminum refineries , world’s ancient and religious heritage monuments Circularity
Antonis Peppas
https://orcid.org/0000-0003-2561-268X
Chrysa Politi
https://orcid.org/0000-0002-7430-5515
Nikolaos Kountouris
Nafsika Angeliki Zafeiri
https://orcid.org/0009-0004-2338-0875
Sotiris Kottaridis
https://orcid.org/0000-0002-0324-2270
Abstract

Primary aluminium industry is one of the largest industries associated with high greenhouse gas emissions. It is reported that in 2022, the aluminium production emitted nearly 270 Mt of direct CO2 in the atmosphere. To achieve the European goals of zero emissions by 2050, a reduction of 4% annually is essential. Τhe industry needs to take a turn towards less impactful production practices, focusing on the valorisation of residues for promoting sustainability. Bauxite residue from alumina production represents a remarkable source of Rare Earth Elements (REEs). This study offers valuable insights into the environmental and economic aspects of processes related to resource Scandium (Sc) extraction and processing in Greece, Romania and Turkey. In this frame, a comparative analysis of the environmental impact of the extraction process of REEs from Bauxite Residues (BR) in the regions mentioned above is presented. The results show that an up to 23% greenhouse gas emissions reduction can be achieved, while the environmental categories of human health risks, aquatic toxicity potential, and terrestrial ecotoxicity potential are improved by applying hydrothermal processes and direct leaching to BR. While the stages of Sc extraction remain consistent, variations in the chemical compositions of BR underscore the influence of local factors. The findings also emphasize the importance of tailoring extraction processes to local conditions and compositions for scandium extraction. These insights can guide industry decisions and contribute to responsible resource management in the future.

Article Details
  • Section
  • Sustainable Development
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References
A. Shen and J. Zhang, “Technologies for CO2 emission reduction and low-carbon development in primary aluminum industry in China: A review,” Renewable and Sustainable Energy Reviews, vol. 189, p. 113965, Jan. 2024, doi:10.1016/J.RSER.2023.113965.
International Aluminium Institute, “Primary Aluminium Production.” [Online]. Available: https://international aluminium.org/statistics/primary-aluminium-production/
R. Simon and T. Vass, “Aluminium - IEA.” [Online]. Available: https://www.iea.org/energy-system/industry/aluminium
“How aluminium is produced,” ALL ABOUT ALLUMINIUM. Accessed: Jan. 28, 2024. [Online]. Available: https://www.aluminiumleader.com/production/how_aluminium_is_produced/
J. C. Wesdock and I. M. F. Arnold, “Occupational and environmental health in the aluminum industry: Key points for health practitioners,” J Occup Environ Med, vol. 56, no. 5, 2014, doi: 10.1097/JOM.0000000000000071.
S. K. Banerjee, “Conversion of conventional wet disposal of red mud into Thickened Tailing Disposal (TTD) at NALCO alumina refinery, Damanjodi.” [Online]. Available: https://www.researchgate.net/publication/279887637_Conversion_of_conventional_wet_disposal_of_red_mud_into_Thickened_Tailing_Disposal_TTD_at_NALCO_alumina_refinery_Damanjodi
K. Evans, “The History, Challenges, and New Developments in the Management and Use of Bauxite Residue,” Journal of Sustainable Metallurgy, vol. 2, no. 4, pp. 316–331, Dec. 2016, doi: 10.1007/s40831-016-0060-x.
T. E. Hövel, “Discussion of Zero Liquid Discharge as a solution for desalination brine management A case study at Desolenator’s project in Dubai,” CHALMERS UNIVERSITY OF TECHNOLOGY, Göteborg, 2021. [Online]. Available: www.chalmers.se
B. Onghena, C. R. Borra, T. Van Gerven, and K. Binnemans, “Recovery of scandium from sulfation-roasted leachates of bauxite residue by solvent extraction with the ionic liquid betainium bis(trifluoromethylsulfonyl)imide,” Sep Purif Technol, vol. 176, pp. 208–219, Apr. 2017, doi: 10.1016/J.SEPPUR.2016.12.009.
J. Anawati and G. Azimi, “Recovery of scandium from Canadian bauxite residue utilizing acid baking followed by water leaching,” Waste Management, vol. 95, pp. 549–559, Jul. 2019, doi: 10.1016/J.WASMAN.2019.06.044.
D. H. Dang et al., “Toward the Circular Economy of Rare Earth Elements: A Review of Abundance, Extraction, Applications, and Environmental Impacts,” Archives of Environmental Contamination and Toxicology, vol. 81, no. 4. Springer, pp. 521–530, Nov.01, 2021. doi: 10.1007/s00244-021-00867-7.
X. Dai et al., “Selective adsorption and recovery of scandium from red mud leachate by using phosphoric acid pre-treated pitaya peel biochar,” Sep Purif Technol, vol. 292, p.121043, Jul. 2022, doi: 10.1016/J.SEPPUR.2022.121043.
D. Hengevoss et al., “Life cycle assessment of a novel production route for scandium recovery from bauxite residues,” Cleaner Waste Systems, vol. 7, p. 100129, Apr. 2024, doi: 10.1016/J.CLWAS.2024.100129.
S. Bobba, S. Carrara, J. Huisman, F. Mathieux, and C. Pavel, Critical Raw Materials for Strategic Technologies and Sectors in the EU. 2020. doi: 10.2873/865242.
Scandium International, “Scandium Markets and Uses | Scandium International Mining Corporation.” [Online]. Available: https://scandiummining.com/products/scandium-markets-and-uses-1/
S. Healy, “SUSTAINABLE BAUXITE RESIDUE MANAGEMENT GUIDANCE,” London, 2022. Accessed: Feb. 07, 2024. [Online]. Available: www.international-aluminium.org
MYTILINEOS S.A., “Aluminium Of Greece.” [Online]. Available: http://www.alhellas.com/
Alum, “Bun venit la Alum S.A.” [Online]. Available: https://www.alum.ro/
ETI ALUMINYUM, “Seydişehir Aluminium Facility.” [Online]. Available: https://www.etialuminyum.com/plants/seydisehir-aluminium-facility/?lang=en
“ISO 14040:2006 - Environmental management — Life cycle assessment — Principles and framework.” Accessed: Jan. 28, 2024. [Online]. Available: https://www.iso.org/standard/37456.html
“ISO 14044:2006 - Environmental management — Life cycle assessment — Requirements and guidelines.” Accessed: Jan. 28, 2024.[Online]. Available: https://www.iso.org/standard/38498.html
“European Platform on LCA | EPLCA.” Accessed: Jan. 28, 2024. [Online]. Available: https://eplca.jrc.ec.europa.eu/
A. Peppas, S. Kottaridis, C. Politi, P. M. Angelopoulos, and M. Taxiarchou, “Multi- Model Assessment for Secondary Smelting Decarbonisation: The Role of Hydrogen in the Clean Energy Transition,” Hydrogen 2023, Vol. 4, Pages 103-119, vol. 4, no. 1, pp.
–119, Jan. 2023, doi: 10.3390/HYDROGEN4010007.
G. A. Blengini et al., “Recovery of critical and other raw materials from mining waste and landfills: State of play on existing practices,” Luxemburg, 2019. doi: 10.2760/494020.
EUROPEAN COMMISSION, “Commission notice on technical guidance on the classification of waste,” Apr. 2018. [Online]. Available: http://ec.europa.eu/environment/waste/hazardous_index.htm.
V. Dentoni, B. Grosso, and G. Massacci, “Environmental sustainability of the alumina industry in Western Europe,” Sustainability (Switzerland), vol. 6, no. 12, pp. 9477–9493, 2014, doi: 10.3390/su6129477.
E. Balomenos et al., “Bauxite Residue (BR) produced by Alumina refineries in Europe,” Sep. 2019.
“DIRECTIVE (EU) 2018/850 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL,” Official Journal of the European Union. Accessed: Feb. 07, 2024. [Online]. Available: https://eur-lex.europa.eu/legal-content/EN/TXT/?uri=celex%3A32018L0850
A. Goronovski, P. J. Joyce, A. Björklund, G. Finnveden, and A. H. Tkaczyk, “Impact assessment of enhanced exposure from Naturally Occurring Radioactive Materials (NORM) within LCA,” J Clean Prod, vol. 172, pp. 2824–2839, Jan. 2018, doi: 10.1016/j.jclepro.2017.11.131.
Alibaba, “Scandium price Suppliers and Manufacturers at Alibaba.com.” [Online]. Available: https://www.alibaba.com/showroom/scandium-price.html