INTERACTION OF CLAY MATERIALS WITH LEAD IN AQUEOUS SOLUTIONS


Published: Jul 28, 2016
Keywords:
palygorskit smectite montmorillonite removal lead
Z. Kypritidou
A. Argyraki
G. Chryssikos
M. Stamatakis
Abstract

Five bulk clay samples were characterized by XRD, XRF, FTIR and SEM and tested for their effectiveness in removing lead ions from aqueous solutions. These were pal ygorskite, smectite and mixed palygorskite/smectite clays from Macedonia, Greece, as well as a montmorillonite-rich sample from Kimolos, Greece, and a palygorskiterich sample from Western Australia]. Lead removal was investigated as a function of the pH and ionic strength of the suspensions, the amount of sorbent and time, at con stant Pb2+ concentration (50mg/L) and temperature (22oC). The greatest potential fo r Pb2+ removal was found for the natural palygorskite/smectite clay

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  • Special Session: Enviromental Geochemistry
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References
Bourliva, A., Michailidis, K., Sikalidis, C., Filippidis, A. and Betsiou, M., 2013. Lead removal from
aqueous solutions by natureal Greek bentonites, Clay Minerals, 48, 771-787.
Christidis, G., 1998. Physical and chemical properties of some bentonite deposits of Kimolos Island,
Greece, Applied Clay Science, 13, 79-98.
Christidis, G., Katsiki, P., Pratikakis, A. and Kacandes, G., 2010. Rheological properties of
palygorskite-smectite suspensions from the Ventzia Basin, W. Macedonia, Greece, Bulletin
of the Geological Society of Greece, Proceedings of the 12th International Congress, Patras.
Chryssikos, G.D., Gionis, V., Kacandes, G.H., Stathopoulou, E.T., Suárez, M., García-Romero, E.,
and Sánchez del Rio, M., 2009. Letter: Octahedral cation distribution in palygorskite,
American Mineralogist, 94(1), 200-203.
Gionis, V., Kacandes, G., Kastritis, I. and Chryssikos, G., 2007. Combined near-infrared and X-ray
diffraction investigation of the octahedral sheet composition of palygorskite, Clays and Clay
Minerals, 55(6), 543-553.
Kastritis, I.D., Kacandes, G.H. and Mposkos, E., 2003. The palygorskite and Mg-Fe-smectite clay
deposits of the Ventzia basin, western Macedonia, Greece, Mineral exploration and sustainable
development, Millpress, Rotterdam, 891-894.
Madejova, J., 2003. FTIR techniques in clay mineral studies: Review, Vibrational Spectroscopy, 31,
-10.
Malamis, S. and Katsou, E., 2013. A review on zinc and nickel adsorption on natural and modified
zeolite, bentonite and vermiculite:Examination of process parameters, kinetics and
isotherms, Journal of Hazardous Materials, 252-253 (Review), 428-461.
Potgieter, J., Potgieter-Vermaak, S. and Kalibantonga, P., 2006. Heavy metals removal from
solution by palygorskite clay, Minerals Engineering, 19, 463-470.
Rhoades, J., 1990. Cation exchange capacity. In: A.L., P., Miller, R. and Keeney, D., eds., Methods
of soil analysis, 2(9), 49-157, Am. Soc. Agr., Soil Sc. Soc. Am, Madison.
Sen Gupta, S. and Bhattacharyya, K., 2011. Kinetics of adsorption of metal ions on inorganic
materials:A review, Advances in Colloid and Interface Science, 162, 39-58.
Stathopoulou, E.T., Suárez, M., García-Romero, E., Del Río, M.S., Kacandes, G.H., Gionis, V. and
Chryssikos, G.D., 2011. Trioctahedral entities in palygorskite: Near-infrared evidence for
sepiolite-palygorskite polysomatism, European Journal of Mineralogy, 23(4), 567-576.
Volkov, A., Paula, S. and Deamer, D., 1997. Two mechanisms of permeation of small neutral
molecules and hydrated ions across phospholipid bilayers, Bioelectrochemistry and
Bioenergetics, 42, 153-160.
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