MINERAL CARBONATION AS A POTENTIAL CARBON DIOXIDE STORAGE OPTION FOR THE REGION OF WESTERN MACEDONIA, GREECE


Published: Jan 1, 2007
Keywords:
chemical fixation reaction kinetics olivine Vourinos ophiolites
N. Koukouzas
H. Ziock
F. Ziogou
I. Typou
Abstract

The long-term storage of the greenhouse gas C02 generated by fossil fuel-fired power plants in the form of stable mineral carbonates appears to be a promising option for reducing global CO2 emissions. In the case of mineral carbonation captured gaseous CO2 is chemically stored in an exothermic reaction by the carbonation of magnesium or calcium silicate minerals, forming environmentally benign and thermodynamically stable products. The purpose of this paper is to give an overview of the carbon dioxide storage by mineral carbonation and to examine the feasibility of this sequestration option in the region of Western Macedonia. The main candidate minerals for carbonation and their sequestration capacity are presented. Furthermore, the most promising mineral carbonation process routes as well as the thermodynamics and kinetics of carbonation reaction are addressed, based on a review on the published literature. In Greece abundant magnesium-rich ultramafic rocks exist that probably could support the national CO2 emissions abatement policy. The attractiveness stems from the favourable geographical relationship between large stationary CO2 emission sources and potential magnesium silicate deposits. Thus, a roughly description of the olivine deposits and their quality in the region of Western Macedonia will be provided

Article Details
  • Section
  • Mineralogy-Petrology-Geochemistry-Economic Geology
Downloads
Download data is not yet available.
References
Brunn, J.H., Argyriadis, I., and Braud, J., 2004. Magmatic emplacement of ophiolites in Northern Greece, Bulletin of the Geological Society of Greece, XXXVI, Proceedings of the 10th International Congress, Thessaloniki, April
Dabitzias, S., and Rassios, Α., 2000. Hartzburgites/dunites for high quality olivine products in the Vourinos and Pindos Ophiolite Complexes, Γ' Conference of Economic Geology, Mineralogy & Geochemistry, Kozani, 330-340.
Goff, F., and Lackner, Κ. S., 1998. Carbon Dioxide Sequestering Using Ultramafic Rocks, Environmental Geoscience, 5(3), 89-101.
Goldberg, P., 2001. C02 Mineral Sequestration Studies in US: Introduction, Issues and Plans, National Energy Technology Laboratory Wortehop on C02 Sequestration with Minerals
.
Haywood, H. M., Eyre, J. M., and Scholes, H., 2001. Carbon dioxide sequestration as stable carbonate minerals-environmental barriers, Environ. Geol., 41, 11-16.
Huijgen, W.J.J., and Comans, R.N.J., 2003. Carbon dioxide sequestration by mineral carbonation, literature review, Energy research Centre of the Netherlands, ECN-C-03-016, Petten, The Netherlands.
IPCC, 2001. Special Report on Carbon Dioxide Capture and Storage, Mineral carbonation and industrial uses of carbon dioxide (Chapter 7).
IPCC/TEAP, 2005. Special Report, Carbon Dioxide Capture and Storage. ISBN 92-9169-119-4.
Koukouzas, N., 1998. Distribution of lignite deposits based on the age, quality and their deposits, Mineral Wealth, 106/1998.
Lackner, K.S., Wendt, C. H., Butt, D. P.; Joyce, E. L., and Sharp, D. H., 1995. Carbon dioxide disposal in carbonate minerals, Energy, 20, 1153-1170.
Lackner, K. S., Butt, D. P., Wendt, C. H., Goff, F., and Guthrie, G., 1997. Carbon Dioxide Disposal in Mineral Form: Keeping Coal Competitive, Tech. Report No. LA-UR-97-2094 (Los Alamos National Laboratory).
Margaras, S., and Vacondios, I., in collaboration with Grivas, E., Konstantopoulou, G., and Rassios, Α., 1996. The Vourinos Ophiolite Complex, Northern Greece.
Mavrides, Α., Skourtsis-Coroneou, V., and Tsalia-Monopolis, S., 1977. Contribution to the geology of the Subpelagonian zone (Vourinos area, West Macedonia). In VI Coll. Aegean region, I, 175-195pp.
Moores, E., 1969. Petrology and structure of the Vourinos ophiolitic complex of Northern Greece. Geol. Soc. Amer. Spec, 118, 74.
Mountrakis, D., 1983. Structural geology of the North Pelagonian zone s.l. and geotectonic evolution of the internal Hellenides. Unpubl. "Habilitation ", Univ. Thessaloniki, Greece, 283pp.
Mountrakis, D., 1986. The Pelagonian zone in Greece: a polyphase deformed fragment of the Cimmerian continent and its role in the geotectonic evolution of East Mediterranean. J. of Geology, 94, 335-347.
O'Connor, W.K., Dahlin, D.C., Rush, G.E., Gedermann, S.J., Penner, L.R., and Nilsen, D.N., 2005. Aqueous mineral carbonation. Final Report, DOE/ARC-TR-04-002.
Psomas, S., 2006. The end of lignite and the transition towards a new energy period, www.greenpeace.com, October 2006, Athens, Greece.
Rassios, Α., Beccaluva, L., Bortolotti, V., Mavrides, A. and Moores, Ε. M., 1983. Vourinos ophiolite complex: field guidebook for workshop on Vourinos Guevgueli ophiolites, IGCP 197,34pp.
Ross, J.V., Mercier, J-CC, Lallement, H.G. Ave, Carter, N.L., and Zimmerman, J., 1980. The Vourinos ophiolite complex, Greece: The tectonic suite, Tectonophysics, 70, 63-83.
Smith, A.G., 1979. Orthris, Pindos and Vourinos ophiolites and the Pelagonian zone. In VI Coll. Aegean region, III, 1369-1374.
Most read articles by the same author(s)