GEOLOGICAL AND MINERALOGICAL CHARACTERIZATION OF SOME ZEOLITIZED TUFFS FROM NWRN TRANSYLVANIA, ROMANIA


H. Bedelean
V. Codrea
Ο. Barbu
Résumé

Zeolites are the most common products of transformation of silicic volcanic glass in the NW-rn part of Transylvania (Romania). Representative samples of volcanic tuffs from Mäcicas (Cluj county) were investigated by using optical (polarized light) microscopy, scanning electron microscopy (SEM), X-ray diffraction (XRD), and wet chemical analyses. The volcanic tuffare vitreous with an acid composition. Vitreous matrix and glass shards are replaced by zeolite minerals, mainly clinoptilolite and trace amounts ofopal-CT and mordenite. X-ray diffraction semiquantitative analysis indicated that clinoptilolite represent between 60 % and 70 % of the crystalline fraction of the tuff. The clinoptilolite content of the Mäcicas tuff deposits is one of the richest in Romania. According to the present status in the zeolite market in Europe, this deposit could have industrial potential in the construction industry and in environmental applications.

Article Details
  • Rubrique
  • Mineralogy-Petrology-Geochemistry-Economic Geology
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Références
Bedelean, I., and Stoici, S., 1984. Zeolitii. Ed. Tehnicä, Bucuresti, 227p.
Colella, C, de'Gennaro, M., and Aiello, R., 2001. Use of zeolitic tuff in building industry. In D.L. Bish and D.W. Ming (eds), Reviews in Mineralogy and Geochemistry, Natural Zeolites, Occurrence, Properties, Applications, vol 45, 551-588pp.
Cosma, R., 1982. Caracteristici calitative, zone de perspectiva si posibilitati de valorifìcare a tufurilor vulcanice din Romania, Mine, Petrol si Gaze, 33/1, 27-30.
Hay, L.R., and Sheppard, A.R., 2001. Occurrence of zeolites in sedimentary rocks: An Overview. In D.L. Bish and D.W. Ming (eds), Reviews in Mineralogy and Geochemistry, Natural Zeolites, Occurrence, Properties, Applications, vol 45, 217-234pp.
Harben, P.W., 2002. The industrial minerals handybook - 4th Edition: A guide to markets, specifications & prices, Surrey, U.K., Industrial Minerals Information, 412 p.
Iijima, Α., 1986. Occurrence of natural zeolites, Nendo Kagaku, 26, 90-103.
Kassoli-Fournaraki, Α., Stamatakis, M., Hall, Α., Filipidis, Α., Michailidis, K., Tsirambides, Α., and Koutles., Th., 2000. The Ca-rich clinoptilolite deposits of Pentalofos, Thrace, Greece.
In C. Colella and FA. Mumpton (eds), Natural Zeolites for the Third Millennium, De Frede Editore, Napoli, Italy, 193-202pp.
Leggo, P.J., Cocheme, J.J., Demant, Α., and Lee, W.T., 2001. The role of argille alteration in the zeolitization of volcanic glass, Mineralogie al Magazine, 65 (5), 653-663.
Marza, I., 1965. Date noi privind petrografia, originea si culoarea tufului de Dej, Studii si Cercetäri de geologie-geofizica-geografie, Bucuresti,, seria Geologie, 10, 1, 237-281.
Marza, I., Anastasiu, Ν., Seghedi, I., Szakacs, ΑΙ., Kovacs, M., Ghergari, L., Bedelean, I., Seclàman, M., Nicolescu, St., Stefänescu, N., and Voiculescu, L., 1991a. On the nomenclature and classification of pyroclastites. In I. Marza (ed.), The Volcanic Tuffs from the Transylvanian Basin, Romania. Special volume, Babes-Bolyai University Cluj-Napoca, 449-464pp.
Marza, I., Codoreanu, FI., Hosu, AL, Pläceanu, M.L., Marian, D., Pop, R., and Tämas, D., 1991b. Caractérisation pétrographique synthétique des tufs volcaniques de la région Dej-Cluj-Napoca et signification volcanologique. In I. Mârza (ed.), The Volcanic Tuffs from the Transylvanian Basin, Romania. Special volume, Babes-Bolyai University Cluj-Napoca, 171-181pp.
Marza, I., and Meszaros, N., 1991. Les tuffs volcaniques de Transylvanie: historié, valeur theoretique et practique dans le developpment de la geologie Transylvaine. In I. Mârza (ed.), The Volcanic Tuffs from the Transylvanian Basin, Romania. Special volume, Babes- Bolyai University Cluj-Napoca, 11-2lpp.
Meszaros, N., and Nicorici, E. (coord), 1976. Pe poteci cu bänutei de piaträ, Ed.Sport-Turism, Bucuresti, 190p.
Meszaros, N., and Filipescu S., 1991. Le nannoplancton du Complex du Tuf de Dej (Ripa Dracului). In I. Mârza (ed.), The Volcanic Tuffs from the Transylvanian Basin, Romania. Special volume, Babes-Bolyai University Cluj-Napoca, 79+8lpp.
Sanders, C, 1998. Tectonics and erosion, competitive forces in a compresive ororgen. A fission track study of the Romanian Carpathians, Ph.D. thesis, Vrije Universiteit Amsterdam, 204 pp.
Seghedi, I., Szakacs, Α., Vanghelie, I., and Costea, C, 2000. Zeolite formation in the Lower Miocene tuffs, north-western Transylvania, Romania, Romanian Journal of Mineralogy, 80, 11-20.
Sheppard, RA., 1991. Zeolitic diagenesis of tuffs in the Miocene Chalk Hills Formation, western Snake River Plain, Idaho, U.S.Geol.Surv.Bull, 1963, 27pp.
Stamatakis, M.G., Fragoulis, D., Chaniotakis, E., Bedelean, I., and Csiris, G., 2000. Clinoptiloliterich tuffs from Greece, Hungary and Romania and their industrial potential as cement additive, Proceedings V.l., of the 3r International Congress on Mineral Wealth, Technical Chamber of Greece, Athens, 451-458
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