A new occurrence of argentopentlandite and gold from the Au-Ag-rich copper mineralisation in the Paliomylos area, Serbomacedonian massif, Central Macedonia, Greece


V. MELFOS
M. VAVELIDIS
K. ARIKAS
Résumé

The Au-Ag-Cu mineralisation in the Paliomylos area is associated with quartz segregations and pegmatoids in the form of boudinaged bodies. The Au, Ag and Cu contents in the ore bodies reach 6.8 ppm, 765 ppm and 0.80 wt%. The ore minerals consist of pyrite, chalcopyrite, sphalerite, pyrrhotite, galena, bismuthinite, argentopentlandite, gersdorffite, cobaltite, aikinite, hessite, native bismuth and gold. Pentlandite contains significant amounts in Ag (13.15 wt%), Au (1.59 wt%) and PGM, demonstrating a formula of Fe5.37 Ni2.56 Ag1.03 Ir0.03 S8.01. On the basis of geological, textural and chemical data, the mineralisation in the studied area was formed under high temperatures.

Article Details
  • Rubrique
  • Geochemistry and Ore Deposit Geology
Téléchargements
Les données relatives au téléchargement ne sont pas encore disponibles.
Références
BRALIA, Α., SABATINI, G. AND TROJA, F. (1979). A revaluation of the Co/Ni ratio in pyrite as geochemical tool in ore genesis problems. Mineral. Deposita, 14, 353-374.
BURG, J.P., GODFRIAUX, I., RICOU, L.E. (1995). Extension of the Mesozoic Rhodope thrust units in the Vertiskos-Kerdilion massifs (Northern Greece). C. R. Acad. Sci. Paris, v.320, series IIa, 889-896.
CRAIG, J.R., KULLERUD, G. (1969). Phase relations in the Cu-Fe-Ni-S system and their application to magmatic ore deposits. Econ. Geol. Monogr., 4, 344-358.
CRISTOFIDES, G., KORONEOS, Α., SOLDATOS, F, ELEFTHERIADIS, G. (2000). Mesozoic magmatism in the area between the Vardar (Axios) zone and the Serbomacedonian massif (Northern Greece). In: "Geology and Metallogeny of the Dinarides and the Vardar Zone", Banja Luka, Sarajevo. The Academy of Sciences and Arts of the Republic of SRDSKA. Collections and Monographs, Volume I, 111-120.
DE WET, A.P (1989). Geology of part of the Chalkidiki Peninsula, northern Greece. Unpubl. Ph.D. thesis, University of Cambridge, U.K., 177p.
DIXON, J.E. AND DIMITRIADIS, S. (1987).The metamorphic evolution of the Serbomacedonian Massif in Greece. Terra Cognita, 7, 106.
KIOURTZOGLOU, E., VAVELIDIS, M., SISMANIDIS, K. (2001). Metal objects' archaeometrical study from ancient Stagira. In: "The Archaeological Work in Macedonia and Thrace 2000" (in press).
KOCKEL, F, MOLLAT, H., WALTHER, H.W. (1977). Erlaeterungen zur geologischen Karte der Chalkdiki und angrenzenden Gebiete (Nord-Griechenland), 1:100.000. Bundesanst. Geowiss. Rohst., Hannover, 1 Karte in 4 Bloettern, 119p.
KONTNY, Α., FRIEDRICH, G., HERZIG, P, KEYSSNER, S. (1994). Argentian-pentlandite-bearing assemblages in metamorphic rocks of the KTB pilot hole, Oberpfalz, Germany. Can. Mineral., 32, 803-814.
KOSTOPOULOS, D., REISCHMANN, T, SKLAVOUNOS, S. (2001). Palaeozoic and Early Mesozoic magmatism and metamorphism in the Serbomacedonian massif, Central Macedonia, Northern Greece. Jour. Conf. Abstracts of EUG 11, April 8-12 2001, Strasbourg (in press)
KOUROU, A. (1991). Lithology, tectonics, geochemistry and metamorphism of a part of the western Vertiskos group. The area NE from lake Koroneia. Unpubl. PhD thesis, Univ. of Thessaloniki, 461pp.
MANDZUIK, Z.L., SCOTT, S.D. (1977). Synthesis, stability, and phase relations of argentian pentlandite in the system Ag-Fe-Ni-S. Can. Mineral., 15, 349-364.
MORALES, S., FENOLL HACH-ALÌ, P. (1996). Hydrothermal argentopentlandite at El Carchón, Southeastern Spain: Mineral chemistry and conditions of formation. Can. Mineral., 34, 939-947.
MPOSKOS, E. (1983a). A mineralogical study of the Au-Ag-Bi-Te-Cu-Co-Ni-As-S ore mineralisation in Macedonia, Greece. Chem. Erde, 42, 281-296p.
MPOSKOS, E. (1983b). A new occurrence of argentian pentlandite from the Koronouda ore mineralisation, Macedonia, Greece. N. Jb. Miner. Mh., 5, 193-200.
PAPADOPOULOS, C. AND KILIAS, A. (1995). Alterbeziehugen zwischen Metamorphose und Deformation im zentralen Teil des Serbomazedonischen Massivs (Vertiskos Gebrige, Nord-Griechenland). Geol. Runds., 74, 77-85.
RICOU, L. -E., BURG, J.P., GODFRIAUX, I., IVANOV, Z. (1998). Rhodope and Vardar: the metamorphic and the olistromatic paired belts related to the Cretaceous subduction under Europe. Geodinamica Acta, 11, 285- 309.
SAKELARIOU, D. (1989). Geologie des Serbomakedonischen Massivs in der nordoestlichen Chalkidiki, NGriechenland. Deformation und Metamorphose. Dokt. Arb. Univ. Mainz, 117p.
SHISHKIN, N.N., MITENKOV, G.A., MIKHAILOVA, VA., RUDASHEVSKII, N.S., SIDOROV, A.F., KARPENKOV, A.M., KONDRAT'EV, A.V, BUD'KO, I.A. (1971). Pentlandite variety rich in silver. Zap. Vses. Mineral. Obshcest., 100, 184-191.
SIDIROPOULOS, N. (1991) Lithology, tectonics, geochemistry and metamorphism of northwestern part of the Vertiskos group. The area of Kroussia mountain north from Kilkis. PhD Thesis, Univ. of Thessaloniki, 592pp.
VAVELIDIS, M. (1994). Au-Ag-bearing mineralisations in the Serbomacedonian massif, Northern Greece. Beih. zum Eur. Jour. Miner., 6, 292.
VAVELIDIS, M., TARKIAN, M. 1995. Mineralogy of the gold-silver-bearing copper mineralised zones in the Paliopyrgos (Nea Madytos-Stanos) area, Northern Greece. N. Jb. Miner. Mh., 3: 133-143.
VAVELIDIS M., KILIAS Α., MELFOS V, SCHMIDT-MUMM A. (1996). New investigations in the Au-Agbearing Cu mineralisation in the Koronouda area, Central Macedonia, Northern Greece. In: Terranes of Serbia. The Formation of the Geologic Framework of Serbia and the Adjacent Regions. Eds. Knezevic & Krstic, 317-322.
VAVELIDIS, M., MELFOS, V., KILIAS, A. (1999). The gold-bearing quartz veins in the metamorphic rocks at the Drakontio area, central Macedonia, northern Greece. In: Mineral Deposits: Processes to Processing (ed: C.J. Stanley et al.) 209-212.
VAVELIDIS, M., MELFOS, V, ARIKAS, K. (2000). Mineralogy and structural control of the Ag-rich copper mineralization in the Serbomacedonian massif, Paliomylos area, Greece. Beih. zum Eur. Jour. Miner., 12, 220.
VITAL, C. (1986). Mineralogical and petrographical investigations of the area between Arnea and Megali Panagia, Chalkidiki peninsula (northern Greece). Unpubl. PhD thesis, ΕΤΗ Zürich, 125 p.
WAGNER G.A., PERNICKA E., VAVELIDIS M., BARANYI I., BASSIAKOS I. (1986). Archaeometallurgische Untersuchungen auf Chalkidiki. Anschnitt, 38, 166-186.
Articles les plus lus par le même auteur ou la même autrice