Y2k... 2000 and dioxins. a part of our natural ecosystem


A. E. TYRPENOU
Résumé

The new millennium, Y2k as it is internationally symbolized, has come closer, and as doomsayers use to say "Plan for the worst in order to hope for the best". Starting up from the scandal of the identification of high concentrations of dioxin residues in foods of animal origin, it is imperative to refer to this group of chemical pollutants which they have been, they are and they will be the focus of the interest for many years to come. Polychlorinated dibenzo-para-dioxins [PCDDs] and polychlorinated dibenzofuranes [PCDFs] are by-products of industrial processes for the production of organochlorine pesticides [OCPs], polychlorinated biphenyls [PCBs], wood conservation industries, chlorine bleaching of pulp and paper industries, but also the result of municipal solid waste management [MSW] with special attention to recycling processes whose environmental emission are extremely high. From the other hand, we should have to realize that dioxins have been a natural contaminant of our environment for more than 60 million years. Taking into consideration the Tolerable Daily Intake [TDI], which has been set to 1 pg-4pg I-TEQ/kg.b.w. [quantity which includes together dioxins, furans and polychlorinated biphenyls], based on their mode of action and toxicity, it is obvious that the measures which the competent authorities of every country have to put in place for the control of raw materials and food of animal origin, should have to be strict, systematic, permanent and reliable so that they safeguard consumer's health as better as they can.

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Références
Κιλικίδης Σ. Οικολογία. Δομή Λειτουργία και Ρύπανση των Οικοσυστημάτων. Θεσσαλονίκη. 1979
ΣΠΑ Αττικής. Αναλυτικό σχέδιο περιφερειακής ανάπτυξης Περιφέρειας Αττικής, προγραμματικής περιόδου 2000-2006. Αττική, Μάρτιος 1999.
EEA. Environment in the European Union at the turn of the Century. European Environmental Organization, ISBN 92-828-6774-9, EEA Copenhagen, pp. 1-43,1999
WHO. Updating and revision of the air quality guidelines for Europe. Report of a WHO Working Group on Volatile Organic Compounds. WHO Regional Office for Europe, Brussels, Belgium 2-6 October 1995.
European Union. The Commission acts to reduce Dioxin emissions from waste incineration plants. IP 98/867, Brussels. 7 October 1998.
Gribble GW. The Future of Chlorine. Earth Day '96. A guide to saving the planet. The Heartland Institute. 1998
Tate CM, Heiny JS. Organochlorine Compounds in Bed Sediment and Fish Tissue in the South Platte River Basin. Archives of Environmental Contamination and Toxicology. 1996,30:62-78.
Ballschmiter K. Persistent, ecotoxic and bioaccumalative compounds and their possible environmental effects. In:IUPAC White Book on Chlorine. Intenational Union of Pure and Applied Chemistry. Pure and Applied Chemistry, 1996, 68[9]: 1771 -1780
Salata GG. Wade TL. Sei ieano JL. Davis JW. Brooks JM. Analysis o( gulf oï Mexico bot tie nose dolphins for organochlorine pesticides and PCBs. Environmental Pollution. 1995,88:167-175
Hagenmaier H, Walezok M. Time Trends in Levels, Patterns and Profiles for PCDD/PCDF in Sediment Cores of Lake Constance. Organohalogen Compounds, 1996, 28:101-104
Hites R. Toxicology (if environmentally persistent chlorinated organic compounds. Pure and Applied Chemistry, 19%, 68[9]: 1791-1799
Eduljee GH. Dyke P. Cains PW. PCDD PCDF releases from various waste management strategies. Warmer Bulletin. No. 46, 1995
CIL UK. The Catalogue of Cambridge Isotope Laboratories. Environmental Contaminant Standards. The British Greyhound Chromatography and Allied Chemicals, UK, 1992
CEPA. Polychlorinated dibenzo-p-dioxinsand Polychlorinated dibenzofurans. "Toxic" Status under CEPA. Canadian Environmental Protection Act, Ottawa. CANADA, 1990
3.7.8-TCDD. 2.3.7,S-Tetrachlorodibenxo-p-dioin. Chem Finder. Com Database and Internet Searching. 1999
TCDD. 2.3.7.8-tetrachlon)dibenzo-p-dioxin |TCDD]. In: The 8th Report on Carcinogens I99S Summary. Eighth Edition. U.S.Department of Health and Human Services National Toxicology Program, pp.195, 1998
Sotnichenko AL ET AL. Water-soluble 2,3,7.8-tetrachlorodibenzo-p-dioxin complex with human alpha-fetoprotein: properties, toxicity in vivo and antitumor activity in vitro. FEBS Lett.. 1999, 30:450[1-2]:49-51
Watanabe S, Kitamura K, Nagahashi M. Effects of dioxins on human health: a review. Journal of Epidemiology, 1999, 9| 11:1-13
de Voogt P. Wells DE. Reutergardh L. Brinkman UATh. Biological activity, determination and occurrence of planar, mono- and di-ortho PCBs. Inter. Journal οί Environ. Chemistry. 1990,40:1-16
Safe S. Polychlorinated biphenvls (PCBs). dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs). and related οnsidera: environmental and mechanistic considerations, which support the development οϊ toxic equivalency factors (TEFs). Crit.Rcv.Toxicologv, 1990, 21:51 -88
Chrompack. High resolution PCB analysis. Chrompack International Β.V., 1992
FSIS 89. Polychlorinated biphenvls in food-UK dietary intakes. Surveillance Information Sheet Number 89. Joint Food Safety and Standards Group. UK 1996
ΑΠΟΦΑΣΗ 1999,55 LEK: Απόφαση Της Επιτροπή; τη; 6ης Αυγού στον 1999. περί τροποποιήσεως τη; Απόφασης 1999 449 ΕΚ για μέτρα προστασίας όσον αφορά τη μόλυνση από διοξίνες ορισμένων προϊόντων ζωικής προέλευσης που προορίζονται για κατανάλωση από τον άνθρωπο ή τα ζώα. Επίσημη Εφημερίδα των Ευρωπαϊκών Κοινοτήτων, L209/42
EUROPEAN COMMISSION. Opinion on dioxins in milk derived from eattle fed on contaminated feed in Belgium. Directorate-General XXIV, Consumer Policy and Consumer Health Prot e et ion. Directorate Β - Scientific opinions on health matters. Unit B3-Managcmcnt of scientific committees II. Scientific Committee on Food. SCF/CS CNTM PCB 4 final. Brussels. 16.6.99
van den Berg M. Birnbaum L. Bosveld ATC, Brunstrom Β, Cook P. Feeley M. Giesy .IP. Hanberg A. Hasegawa R, Kennedy SW. Kubian T, Larsen JC, van Leeuwen FXR. Liem AKD, Nolt C, Petersen RE, Poellinger L, Safe S. Schrenk D, Tillitt D, Tysklind M, Younes M. Worn F. Zacharewski T. Toxic Equivalency Factors (TEFs) for PCBs. PCDDs, PCDFs for Humans and Wildlife. Environ. Health Perspect.. 1998. 106:775-792
Wiesmuller T, Schiatterei- Β. Wuntke Β, Schneider R. PCDDs PCDFs. Copanar PCBs and PCBs in Barn Owl Eggs from Different Areas in the State oï Brandendurg, Germany. Bulletin of the Environmenta Contamination and Toxicology, 1999,63:15-24
IARC. Polychlorinated Dibenzo-para-dioxinsand Polychlorinated Dibenzofurans. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans. ISBN 92 832 1269 . 1997
Almasi E. Brittain R, Sheehan T, Xila L. Determination of Polychlorinated dibenzo-p-dioxins [PCDDs] and dibenzofurans f PCDFs]: GC/MS/MS analysis with VARIAN Ion Trap GC/MS. VARIAN Chromatography Systems R&D Laboratory. USA. 1999
WHO. WHO toxic equivalency factors (TEFs) for dioxin-like compounds for humans and wildlife. L5-18 June 1999, Stockholm. Sweden. 1999
US EPA. Interim procedures for estimating risks associated with exposures to mixtures of chlorinated dibenzo-p-dioxines and -dibenzofurans (CDDs and CDFs) and 1989 update. U.S.Environmental Protection Agency. Risk .Assessment Forum, Washington. DC; EPA/625/3-89/016, 1998
Ahlborg VG. Becking GC, Birnbaum LS. Brower A. Derks HJGM, Free lev M. Color C, Hanberg A, Larsen JC. Liem AKD, Sale SH.Schaltter C, Waern F, Younes M. Yrankeikki
E. Toxic equivalency factors for dioxin-like PCBs. Chemosphere. 1994,28[6|: 1049-1067
US EPA. Dose-Response Modeling for 2,3.7.
Ramos L. Eljarrat E, Hernandez LM, Rivera J, Gonzalez MJ. Levels oï PCBs, PCDDs and PCDFs in commercial butter samples in Spain. Chemosphere, 1999, 3S[ I3|: 3141-3153
Domingo JL. Schuhmacher M, Granerò S, Llobet JM. PCDDs and PCDFs in food samples from Catalonia, Spain. An assessment of dietary intake. Chemosphere, 1999, 38[ 15]:3517-3528
Schecter Α. Cramer P. Boggess Κ, Stanley J. Olson JR. Levels of dioxins, dibenzofurans, PCB and DDE congeners in pooled food samples collected in 1995 at supermarkets across thw United States. Chemosphere. 1997.34:1437-1447
Jimenez B. Wright C, Kelly M. Startin JR. Levels of PCDDs. PCDFs and non-ortho PCBs in dietary supplement fish oil obtained in Spain. Chemosphere. 1996. 32(3 ):461-467
ΕΦΗΜΕΡΙΔΑ TO ΒΗΜΑ. Καθαρά από διοξίνες τά πρώτα δείγματα. Εφημερίδα το ΒΗΜΑ. 28.7.99
ΕΦΗΜΕΡΙΔΑ ΕΞΠΡΕΣ. Πρώτης ποιότητας τα ελληνικά προϊόντα Εφημερίδα ΕΞΠΡΕΣ. 30.7.99
Mukerjee D. Health impact of polychlorinated dibenzo-pdioxins: a critical review. J. Air Waste Management Association. 1998. 4S[2]: 157-165
Pollack M. PRO/AH>Dioxin health assessment (03). News media & Dawn Newspapers, pp. 1-3. Belgium. 1999
Gribble GW. Earth Day "96. A guide to saving the Planet. The Future of Chlorine. American Council on Science and Health [ACSH], 1998
Constans DL. Dioxins-Primer and Commentary. Gossman Consulting Inc. Publication. 1996.2(05]: 1-3.
Erickson B. Environmental Protection Agency. Today's Chemist at Work. 1999. 8[3]: 101-124
Hayward DG. Quatropole Ion Storage Mass Spectrometry/Mass Spectrometry Application to the Analysis of all 17 2.3,7,8 substituted Chlorodibenzo-p-dioxins (dioxins) and Chlorodibenzofurans (furans) in Dairy Products and High Fat Foods. Laboratory Information Bulletin No.4084 Dioxins, Division for Field Science, ORA - Center for Food Safety and Applied Nutrition. U.S.FDA. 1997
Ballschmiter K. Analysis of Polyhalogenated Dioxins and Furans (HalxDD/HalxDF; Hal = Br, CI;) Routine and Unsolved Problems. In: Heidelore F., Hartmut F.. Otto Η. Wolfram P.. Alarich R.. Stephen S. (eds) DIOXIN '93. 13th International Symposium on Chlorinated Dioxins and Related Compounds-Organohalogen Compounds. Volume 11. Vienna. September 1993
WHO. WHO experts re-evaluate health risks from dioxins. Press Release WHO/45,3 June 1998
Perkins PD. 1998. The Analysis of Dioxin Using a Benchtop Mass Spectrometer. Application Brief. Hewlett Packard Company USA. 1998
EPA Method 1613. Tetra- through Octa-Chorinated Dioxins and Furans by Isotope Dilution HRGC HRMS. U.S.Environmental Protection Agency. Office of Water. Engineering and Analysis Division (4303) 401 M. Street S.W.Washington. D.C. 20460, 1994
EPA Method 613. Methods for organic chemical analysis of municipal and industrial wastewater. Appendix to Part 136. 2.3.7,8 - Tetrachlorodibenzo-p-dioxin, 1994
EPA Method 8280A. The analysis of polychlorinated dibenzop-dioxins and polychlorinated dibenzofurans by High Resolution Gas Chromatography/ Low Resolution Mass Spectrometry (HRGC/LRMS). Revision 1, 1996
Krahn MM. Ylitaio GM, Buzitis J, Sloan CA. Boyd DT. Lam Chan S. Varanasi U. Screening for planar chlorobiphenyl congeners in tissues of marine biota by high-performance liquid chromatography with photodiode array detection. Chemosphere. 1994, 29:117-139.
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