Trace metal concentrations in the offshore surficial sediment of the Heraklio Gulf (Crete Island, East Mediterranean Sea)


Опубликован: Μαρ 28, 2020
IOLI NIKOLETTA KOUKOUNARI
VASSILIKI PARASKEVOPOULOU
https://orcid.org/0000-0002-5139-798X
AIKATERINI KARDITSA
PANAYOTA KOULOURI
SERAFEIM POULOS
COSTAS DOUNAS
MANOS DASSENAKIS
Аннотация

The present study investigates the distribution of trace metals (Fe, Mn, Cr, Zn, Pb, Cu and Al), as indicators of pollution, in the surficial inner shelf sediments along the northern coast of Heraklio Gulf (Crete Island). Despite the fact that Heraklio Gulf is an industrialized urban area, hosting the third most important commercial harbour in Greece, the levels of trace metals in sediments are not exceedingly high. According to Sediment Quality Guidelines (SQG’s), the sediments are considered unpolluted with low probability of adverse effects to biota in the case of Cu, Zn and Pb, while moderately to heavily polluted only in the case of Cr. Moreover, Zn, Cu and Pb concentrations are lower than those measured in a previous study (1989). This improvement of environmental state in the study area is a response to more effective control of terrestrial pollution sources, following the enforcement of the Directive 91/271/EEC (as amended by Directive 98/15/EU) on urban wastewater treatment and disposal into Greek national legislation.

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Биография автора
VASSILIKI PARASKEVOPOULOU, Laboratory of Environmental Chemistry, Department of Chemistry, National & Kapodistrian University of Athens, Panepistimioupoli-Zografou, GR-15784, Attiki
Εργαστήριο Χημείας Περιβάλλοντος, Τμήμα Χημείας, ΕΚΠΑ, Ερευνητικό Διδακτικό Προσωπικό (ΕΔΙΠ),
Библиографические ссылки
Alexandrakis, A., Ghionis, G., Poulos, S.E., 2013. The effect of beach rock formation on the morphological evolution of a beach. The case study of an Eastern Mediterranean beach: Ammoudara, Greece. Journal of Coastal Research, 69 (sp1), 47-59.
Anagnopoulos N., Anastasakis G, Bourdaniotis N., Dassenakis M., Demetriou P., et al., 2012. Technical Report for the preparation stage of Action Plan for the Marine Strategies in Greece, for the implementation of Marine Strategy Framework Directive 2008/56/EC, in the framework of the project ‘Technical Advisor of the Special Secretariat for Water for the implementation of MSFD (2008/56/EC) (Ministry of Environment, Energy and Climate Change)’, Athens (in Greek).
Athanasoulis G.A., Skarsoulis E.K., 1992. Wind and Wave Atlas of the Northeastern Mediterranean Sea. National Technical University of Athens, Greece, 191 pp.
Balkis, N., Ҫağatay M.N., 2001. Factors controlling metal distribution in the surface sediments of the Erdek Bay, Sea of Marmara, Turkey. Environment International, 27, 1-13.
Bianchi, T. S., Allison, M. A. 2009. Large-river delta-front estuaries as natural “recorders” of global environmental change. Proceedings of the National Academy of Sciences of the United States of America, 106 (20), 8085-8092.
Buchman, M.F., 2008. NOAA Screening Quick Reference Tables, NOAA OR&R Report 08-1, Seattle WA, Office of Response and Restoration Division, National Oceanic and Atmospheric Administration, 34 pp. (available at http:// response.restoration.noaa.gov/ environmental-restoration/ environmental-assessment-tools/squirt-cards.html).
Calvert, S.E., Mukherjee, S., Morris, R.J., 1985. Trace metals in humic and fulvic acids from modem organic-rich sediments. Oceanologica Acta, 8, 167-173. CCME (Canadian Council of Ministers of the Environment). 1995. Protocol for the derivation of Canadian sediment quality guidelines for the protection of aquatic life. CCME EPC-98E. Prepared by Environment Canada, Guidelines Division, Technical Secretariat of the CCME Task Group on Water Quality Guidelines, Ottawa. [Reprinted in Canadian environmental quality guidelines, Chapter 6, Canadian Council of Ministers of the Environment, 1999, Winnipeg.]
Christophoridis, C., Dedepsidis, D., Fytianos, K., 2009. Occurrence and distribution of selected heavy metals in the surface sediments of Thermaikos Gulf, N. Greece. Assessments using pollution indicators. Journal of Hazardous Materials, 168, 1082-1091.
Chronis, G., Lykousis, V., Anagnostou, C., Karageorgis, A., Stavrakakis, S. et al., 2000. Sedimentological processes in the southern margin of the Cretan Sea (NE Mediterranean). Progress in Oceanography, 46 (2-4), 143-162.
Dagg, M., Benner, R., Lohrenz, S., Lawrence, D., 2004. Transformation of dissolved and particulate materials on continental shelves influenced by large rivers: plume processes. Continental Shelf Research, 24 (7-8), 833-858.
Dassenakis, M., Andrianos, H., Depiazi, G., Konstantas, A., Karabela, M. et al., 2003. The use of various methods for the study of metal pollution in marine sediments, the case of Euvoikos Gulf, Greece. Applied Geochemistry, 18, 781-794.
Duman, M., Duman, S., Lyons, T., Avci, M., Izdar, E. et al., 2006. Geochemistry and sedimentology of shelf and upper slope sediments of the south-central Black Sea. Marine Geology, 227, 51-65.
Duman, M., Kucuksezgin, F., Atalar, M., Akcali, B., 2012. Geochemistry of the northern Cyprus (NE Mediterranean) shelf sediments: implications for anthropogenic and lithogenic impact. Marine Pollution Bulletin, 64 (10), 2245-2250.
Dounas, C., Papadopoulou, K., 1993. Oceanographic and environmental study of Iraklion Bay. Institute of Marine Biology of Crete, HCMR, Technical report, Greece, 93 pp. (in Greek). EEA- European Environment Agency, 2008. Coasts and Seas. Copenhagen, Luxembourg, Office for Official Publications of the European Communities, 9 pp. https://www.eea.europa. eu/themes/water/europes-seas-and-coasts (Accessed 27 January 2019).
El-Geziry, T.M., Bryden, I.G., 2010. The circulation pattern in the Mediterranean Sea: issues for modeller consideration. Journal of Operational Oceanography, 3 (2), 39-46.
El Nemr, A.M., El Sikaily, A., Khaled, A., 2007. Total and leachable heavy metals in muddy and sandy sediments of Egyptian coast along Mediterranean Sea. Environmental Monitoring Assessment, 129 (1-3), 151-168.
Eurostat, 2013. Coastal region statistics, Eurostat Statistics Explained (2013). http://ec.europa.eu/eurostat/statistics-explained/ index.php/Coastal_regions_-_population_statistics (Accessed 27 January 2019).
Folk R.L., 1980. Petrology of sedimentary rocks. Hemphill, Austin, 182 pp. GESAMP/UNESCO, 1994. Anthropogenic influences on sediment discharge to the coastal zone and Environmental Consequences. Reports and Studies, 52, 4-30.
Goudeau, M.L.S., Grauel, A.L., Bernasconi, S.M., de Lange, G.J., 2013. Provenance of surface sediments along the southeastern Adriatic coast off Italy: An overview. Estuarine Coastal and Shelf Science, 134, 45-56.
Horowitz, A.J., Elrick, K.A., 1987. The relation of stream sediment surface area, grain size and composition to trace element chemistry. Applied Geochemistry, 2 (4), 437-451. HNHS (Hellenic Navy Hydrographic Service), 2005. Tides and tidal data for Greek harbours, (4th ed.) Hellenic Navy Hydrographic Service, Athens (in Greek).
Iatrou, M., Papatheodorou, G., Geraga, M., Ferentinos, G., 2010. The study of heavy metal concentrations in the red mud deposits at the Gulf of Corinth, using multivariate techniques, Bulletin of the Geological Society of Greece, Proceedings of the 12th International Congress, Patras, May 2010, 20XLIII(2), 1018-1028. Jackson, M.L., 1958. Soil Chemical Analysis. Prentice-Hall, Inc., Englewood Cliffs, NJ, 521 pp.
Karageorgis, A.P., Anagnostou, C.L., Kaberi, H., 2005. Geochemistry and mineralogy of the NW Aegean Sea surface sediments: implications for river runoff and anthropogenic impact. Continental Shelf Research, 20, 69-88.
Karditsa, A., Poulos, S.E., 2013. Sedimentological investigations in a river-influenced tideless coastal embayment: The case of inner continental shelf of the NE Aegean Sea Continental Shelf Research, 55, 86-96.
Karditsa, A., Poulos, S.E., Botsou, F., Alexakis, D., Stamatakis, M., 2014. Investigation of major and trace elements distribution pattern and pollution status of the surficial sediments of a microtidal inner shelf influenced by a transboundary river. The case of the Alexandroupolis Gulf (northeastern Aegean Sea, Greece). Journal of Geochemical Exploration, 146, 105-118.
Komar, P.D., 1976. Beach processes and sedimentation. Prentice Hall, Englewood Cliffs, NJ, 429 pp. Long, E.R., MacDonald, D.D., Smith, S.L., Calder, F.D., 1995. Incidence of adverse biological effects within ranges of chemical concentrations in marine and estuarine sediments, Environmental Management, 19 (1), 81-97.
Long, E.R., Wilson, C.J., 1997. On the Identification of Toxic Hot Spots using Measures of the Sediment Quality Triad. Marine Pollution Bulletin, 34 (6), 373-374.
Loring, D.H., Rantala, R.T.T., 1992. Manual for the geochemical analyses of marine sediments and suspended particulate matter, Earth-Science Reviews, 32 (4), 235-283.
Luo, C.L., Shen, Z.G., Li, X.D., Baker, A.J.M., 2006. Enhanced phytoextraction of Pb and other metals from artificially contaminated soils through the combined application of EDTA and EDDS. Chemosphere 63, 1773-1784.
MacDonald, D.D., Ingersoll, C.G., Berger, T.A., 2000. Development and evaluation of consensus-based sediment quality guidelines for freshwater ecosystems. Archives of Environmental Contamination and Toxicology, 39, 20-31.
Magesh, N.S., Chandrasekar, N., Roy, D.V, 2011. Spatial analysis of trace element contamination in sediments of Tamiraparani estuary, southeast coast of India,Estuarine, Coastal and Shelf Science, 92 (4), 618-628.
Mathes, E.S., Rasmussen, T.C., 2006. Combining multivariate statistical analysis with geographic information systems mapping: a tool for delineating groundwater contamination. Hydrogeology Journal, 14, 1493-150.
Morillo, J., Usero, J., Gracia I., 2004. Heavy metal distribution in marine sediments from the southwest coast of Spain. Chemosphere, 55, 431-442.
Nichols, S.J., Manny, B.A., Schloesser, D.W., Edsall, T.A., 1991. Heavy metal contamination of sediments in the Upper Connecting Channels of the Great Lakes. Hydrobiologia, 219, 307‐315.
Nittis, K., Zervakis, V., Papageorgiou, E., Perivoliotis, L., 2002. Atmospheric and oceanic observations from the POSEIDON buoy network: initial results. The Global Atmosphere and Ocean System, 8, 87-99.
Pappa, F.K., Tsabaris, C., Ioannidou, A., Patiris, D.L., Kaberi, H. et al., 2016. Radioactivity and metal concentrations in marine sediments associated with mining activities in Ierissos Gulf, North Aegean Sea, Greece. Applied Radiation and Isotopes, 116, 22-33.
Paraskevopoulou V., 2009. Distribution and chemical behaviour of heavy metals in sea area affected by industrial pollution (NW Saronikos). Unpublished PhD Thesis in Chemical Oceanography, National and Kapodistrian University of Athens [in Greek].
Pedersen, T.F., Price N.B., 1982. The geochemistry of manganese carbonate in Panama Basin sediments. Geochimica et Cosmochima Acta, 46, 59-68.
Poulos, S.E., 2009. Origin and distribution of the terrigenous component of the unconsolidated surface sediment of the Aegean floor: A synthesis. Continental Shelf Research, 29 (16), 2045-2060.
Poulos, S.E., Dounas, C.G, Alexandrakis, G., Koulouri, P., Drakopoulos, P., 2002. Trace metal distribution in sediments of northern continental shelf of Crete Island, Eastern Mediterranean. Environmental Geology, 58, 843-857.
Saccà, C., Saccà, D., Nucera, P., De Fazio, A., 2011. Composition and geochemistry of clay sediments offshore the northeastern Sicilian coast (Southeastern Tyrrhenian Sea, Italy). Estuarine Coastal and Shelf Science, 92 (4), 564-572.
Salomons, W., Fӧrstner, U., 1984. Metals in the Hydrocycle. Springer-Verlag, Berlin, 349 pp.
Scoullos, M., Sakellari, A., Giannopoulou, K., Paraskevopoulou, V., Dassenakis, M., 2006. Dissolved and particulate trace metal levels in the Saronikos Gulf, Greece, in 2004. The impact of the primary Wastewater Treatment Plant of Psittalia. Desalination, 210, 98-109.
Smith, W., McIntyre, A.D., 1954. A spring-loaded bottom sampler. Journal of the Marine Biological Association UK, 33, 257-264.
Squadrone, S., Brizio, P., Stella, M., Pastorino, P., Serracca, L. et al., 2016. Presence of trace metals in aquaculture marine ecosystems of the northwestern Mediterranean Sea (Italy). Environmental Pollution, 215, 77-83.
Sutherland, R.A., 2000. Bed sediment-associated trace metals in an urban stream, Oahu, Hawaii. Environmental Geology, 39 (6), 611-627.
Tsimplis M.N., 1994. Tidal Oscillations in the Aegean and Ionian Seas. Estuarine, Coastal and Shelf Science, 39 (2), 201-208.
Walkley, A., 1947. A critical examination of a rapid method for determining organic carbon in soils: Effect of variations in digestion conditions and of inorganic soil constituents. Soil Science, 63, 251-263.
Xie, Y., Chen, T., Lei, M., Yang, J., Guo, Q.-J. et al., 2011. Spatial distribution of soil heavy metal pollution estimated by different interpolation methods: Accuracy and uncertainty analysis. Chemosphere, 82 (3), 468-476.
Zervakis. V., Nittis, K., Theocharis, A., Georgopoulos, D., 1998. The interactive relation of water column structure and mesoscale circulation in the Cretan Sea during the last decade. Paper presented at EGS VVIII General Assembly Nice, France 20-24, April 1998.
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