POTENTIAL TOXIC ELEMENTS (PTES) IN GROUND AND SPRING WATERS, SOILS AND SEDIMENTS: AN INTERDISCIPLINARY STUDY IN ANTHEMOUNTAS BASIN, N. GREECE


Published: Jul 28, 2016
Keywords:
Arsenic Nickel Travertine Geothermal water Faults Ophiolites
N. Kazakis
N. Kantiranis
M. Kaprara
M. Mitrakas
G. Vargemezis
K. Voudouris
A. Chatzipetros
K. Kalaitzidou
A. Filippidis
Abstract

Ground and spring waters, soils and sediments of Anthemountas basin in Northern G reece were analyzed for Potential Toxic Elements (PTEs). In total, twenty three soil and sediment samples, three groundwater (boreholes) and two spring water samples, were analyzed. Contents of Ni in soils and sediments can be as high as 2169 mg/kg. The high correlation coefficient of Ni and Cr, indicates the geogenic origin of Ni, which originates from ophiolitic rocks. Arsenic concentration ranges from 3 to 110 mg/kg in soils and sediments, with the highest contents observed in travertine. The spring waters are characterized by elevated concentrations of As (up to 235 μg/L), N a, K, Fe and Zn, indicating that hydrothermal fluids are responsible for feldspar alte ration of the Monopigado granodiorite. On the contrary, in groundwaters, As conten ts are low (up to 18 μg/L). Electrical resistivity tomographies performed around the groundwater boreholes, revealed the presence of normal faults, locally allowing the mixing of geothermal fluids with the shallow porous aquifer (SPA). The presence of As in the SPA is probably due to inputs from geothermal waters through normal faulting.

Article Details
  • Section
  • Special Session: Enviromental Geochemistry
Downloads
Download data is not yet available.
References
Assubaie, F.N., 2015. Assessment of the levels of some heavy metals in water in Alahsa Oasis farms,
Saudi Arabia, with analysis by atomic absorption spectrophotometry, Arabian Journal of
Chemistry, 8, 240-245.
Chowdhury, T.R., Basu, G.K., Mandal, B.K., Biswas, B.K., Samanta, G., Chowdhury, U.K.,
Chanda, C.R., Lodh, D., Roy, S.L., Saha, K.C., Roy, S., Kabir, S., Quamruzzaman, Q. and
Chakraborti, D., 1999. Arsenic poisoning in the Ganges Delta, Nature, 401, 545-546.
Clesceri, L., Greenberg, A. and Trussell, R., 1989. Standard Methods for the Examination of Water
and Wastewater, 17th edition. APHA-AWWA-WEF, Washington DC.
Dermatas, D., Mpouras, T., Chrysochoou, M., Panagiotakis, I., Vatseris C., Linardos, N.,
Theologou, E., Boboti, N., Xenidis, A., Papassiopi, N. and Sakellariou, L., 2015. Origin and
concentration profile of chromium in a Greek aquifer, Journal of Hazardous Materials, 281,
-46.
Esmaeili, A., Moore, F., Keshavarzi, B., Jaafarzadeh, N. and Kermani, M., 2014. A geochemical
survey of heavy metals in agricultural and background soils of the Isfahan industrial zone,
Iran, Catena, 121, 88-98.
Fantoni, D., Brozzo, G., Canepa, M., Cipolli, F., Marini, L., Ottonelo, G., Vetuschi and Zuccolini,
M., 2002. Natural hexavalent chromium in groundwaters interacting with ophiolitic rocks,
Environmental Geology, 42(8), 871-882.
Gallego, J.L.R., Ordonez, A. and Loredo, J., 2002. Investigation of trace element sources from an
industrialized area (Aviles, northern Spain) using multivariate statistical methods, Environ.
Int., 27, 589-596.
Gamaletsos, P., Godelitsas, A., Dotsika, E., Tzamos, E., Gotthlicher, J. and Filippidis, A., 2013.
Geological sources of As in the Environment of Greece: A review. In: The Handbook of
Environmental Chemistry, vol. 40. Threats to the Quality of Groundwater Resources:
Prevention and Control, Scozzari, A. and Dotsika, E., eds., Springer-Verlag, Berlin
Heidelberg, 77-113.
Harvey, C.F., Swartz, C.H., Badruzzaman, A.B.M., Keon-Blute, N., Yu, W., Ali, M.A., Jay, J.,
Beckie, R., Niedan, V., Brabander, D., Oates, P.M., Ashfaque, K.N., Islam, S., Hemond, H.F.
and Ahmed, M.F., 2002. Arsenic mobility and groundwater extraction in Bangladesh,
Science, 298, 1602-1606.
Kazakis, N., 2013. Groundwater Pollution Risk Assessment in Anthemountas Basin, PhD thesis,
Department of Geology, Aristotle University of Thessaloniki (in Greek).
Kazakis, N., Kantiranis, N., Voudouris, K.S., Mitrakas, M., Kaprara, E. and Pavlou, A., 2015.
Geogenic Cr oxidation on the surface of mafic minerals and the hydrogeological conditions
influencing hexavalent chromium concentrations in groundwater, Science of the Total
Environment, 514, 224-238.
Kaprara, E., Kazakis, N., Simeonidis, K., Coles, S., Zoumboulis, A.I., Samaras, P. and Mitrakas,
M., 2015. Occurrence of Cr (VI) in drinking water of Greece and relation to the geological
background, J. Hazard. Materials, 281, 2-11.
Katsoyiannis, I., Hug, S., Ammann, A., Zikoudi, A. and Hatziliontos, C., 2007. Arsenic speciation
and uranium concentrations in drinking water supply wells in Northern Greece: Correlation
s with redox indicative parameters and implications for groundwater treatment, Science of
the Total Environment, 383, 128-140.
Kim, J.H., 2009. DC2DPro-2D Interpretation System of DC Resistivity Tomography, User’s
Manual and Theory, KIGAM, S. Korea.
Linos, A., Petralias, A., Christophi, C.A., Christoforidou, E., Kouroutou, P., Stoltidis, M.,
Veloudaki, A., Tzala, E., Makris, K.C. and Karagas. M.R., 2011. Oral ingestion of hexavalent
chromium through drinking water and cancer mortality in an industrial area of Greece - an
ecological study, Environ., Health 10(50), 1-8.
Loke, M.H., 2011. Electrical resistivity surveys and data interpretation. In: Gupta, H.K., ed.,
Encyclopedia of Solid Earth Geophysics. 2nd edition, Springer, 276-283.
Mandal, B.K. and Suzuki, K.T., 2002. Arsenic round the world: a review, Talanta, 58, 201-235.
McCleskey, R.B., Nordstrom, D.K. and Maest, A.S., 2004. Preservation of water samples for
arsenic(III), Applied Geochemistry, 19, 995-1009.
Methods of Soil Analysis, 1996. Part 3 - Chemical Methods. In: Sparks, D.L., ed., Soil Science
Society of America, Madison, WI, USA.
Michard, A., Feinberg, H. and Montigny, R., 1998. The Chalkidiki supra-ophiolitic formations, and
their bearing on the Vardarian obduction process, Bull. Geol. Soc. of Greece, 32(1), 59-64.
Micó, C., Recatalá, L., Peris, M. and Sánchez, J., 2006. Assessing heavy metal sources in
agricultural soils of an European Mediterranean area by multivariate analysis, Chemosphere,
, 863-872.
Mitrakas, M., 2001. A survey of arsenic levels in tap, underground, and thermal mineral waters of
Greece, Fresenius Environmental Bulletin, 10(6), 717-721.
Morrison, G.M.P., Revitt, D.M. and Ellis, J.B., 1990. Metal Speciation in Separate Stormwater
Systems, Water Science Technology, 22, 53.
Nimik, D.A., Moore, J.N., Dalby, C.E. and Savka, M.W., 1998. The fate of geothermal arsenic in
the Madison and Missouri Rivers, Montana and Wyoming, Water Resources Research,
(11), 3051-3067.
Nimfopoulos, M.K., Hadjispyrou, S.A., Polya, D.A., Michailidis, K.M. and Trontsios, G., 2002.
Geochemical conditions and environmental pollution from hydrothermal waters of the
Anthemous basin, Thessaloniki district, N. Greece, 6th Pan-Hellenic Geographical
Conference (Volume II), Thessaloniki 2002, 428-435.
Papastergios, G., Filippidis, A., Fernandez-Turiel, J.L., Gimeno, D. and Sikalidis, C., 2011. Surface
soil geochemistry for environmental assessment in Kavala Area, northern Greece, Water, Air,
& Soil Pollution, 216, 141-152.
Petrotou, A., Skordas, K., Papastergios, G. and Filippidis, A., 2012. Factors affecting the distribution
of potentially toxic elements in surface soils around an industrialized area of northwestern
Greece, Environmental Earth Sciences, 65, 823-833.
Pique, A., Grandia, F. and Canals, A., 2010. Processes releasing arsenic to groundwater in the Caldes
de Malavella geothermal area, NE Spain, Water Research, 44, 5618-5630.
Rodríguez Martín, J.A., Vázquez de la Cueva, A., Grau Corbí, J.M. and López Arias, M., 2007.
Factors controlling the spatial variability of copper in topsoils of the Northeastern Region of
the Iberian Peninsula, Spain, Water, Air, & Soil Pollution, 186, 311-321.
Voudouris, K., Melfos, V., Aidona, E., Kazakis, N., Giouri, K. and Stratis, J., 2014. Arsenic concentration
in groundwater and sediments of Velestino area, Thessaly, Central Greece. Proc. of 10th
International Hydrogeological Conference, 8-10 October 2014, Thessaloniki, 1, 759-770.
Skordas, K., Papastergios, G. and Filippidis, A., 2013. Major and trace element contents in apples from
a cultivated area of central Greece, Environ. Monitoring & Assessment, 185, 8465-8471.
Tzamos, E., Tziritis, E., Vogiatzis, P., Matzari, C., Kantiranis, N., Filippidis, A., Theodosiou, N. and
Fytianos, K., 2014. Suitability of potable groundwater reserves of Thermi Municipality
(Macedonia, Northern Greece) and definition of main hydrogeochemical signatures, Proc. of 12th
Intern. Conf. “Protection & Restoration of the Environment”, Skiathos, 6-3 July, 272-276.
Tziritis, E., Tzamos, E., Vogiatzis, P., Matzari, C., Kantiranis, N., Filippidis, A., Theodosiou, N. and
Fytianos, K., 2015. Quality assessment and hydrogeochemical status of potable water
resources in a suburban area of northern Greece (Thermi Municipality, central Macedonia),
Desalination and Water Treatment, doi: 10.1080/19443994.2015.1052993.
Zhang, C., Selinus, O. and Kjellstrom, G., 1999. Discrimination between natural background and
anthropogenic pollution in environmental geochemistry - exemplified in an area of southeastern
Sweden, Science of the Total Environment, 243-244, 129-140.
Most read articles by the same author(s)