ORGANIC POLLUTANTS IN THE INDUSTRIAL AREA EAST OF KAVALA, NORTHERN GREECE


A. Grigoriadou
A. Georgakopoulos
J. Schwarzbauer
A. Kassoli-Fournaraki
A. Filippidis
G. Papastergios
Abstract

The occurrence and distribution of organic pollutants were studied at in an industrial area situated at the coastal zone east of Kavala, Northeastern Greece. The study focused especially on the area, where the oil facilities of Kavala Oil Co. are located. Three surface water samples were collected and investigated by means of non-target screening analyses to evaluate the level of organic pollution, as well as to reveal molecular markers representing the industrial emissions. The analytical procedure included a sequential extraction of the samples, GC-FID as well as GC/MS analyses (Franke et al., 1995). In the three water samples halogenated compounds, technical additives and synthetic fragrances, phosphates, phthalates, benzothiazoles, esters, ketones, phenols, ethers and PAH's were detected. Quantitative analyses of selected pollutants were additionally performed. Source-specific marker compounds were identified and used to trace different types of emissions throughout the affected environment

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  • Environmental Geology
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References
A.T.S.D.R. (1990). Agency for Toxic Substances and Disease Registry (A.T.S.D.R.). Toxicological Profile for Bromoform. U.S. Public Health Service, U.S. Department of Health and Human Services, Atlanta, GA. 1990.
E.C.L. (1996). European Community Legislation Official Journal of the European Communities, No L 275 (28 Oct 1996). Publication of Annexes A and Β to Council Directive 94/55/EC of 21 November 1994.
EUROCONSULTANTS, S.A. (2001). Terra CZM Project: Integrated management plan for the Kavala Prefecture Coastal zone, 53 pp.
EX.TOX.NET. (2004). Extension Toxicology Network. Internet link: http://extoxnet.orst.edu/pips/thiram.htm. [Search: 3/2004]
Franke, S., Hildebrandt, S., Schwarzbauer, J., Link, M., France, W. (1995). Organic compounds as contaminants of the Elbe river and its tributaries. Fresenius Journal of Analytical Chemistry, 353, 39-49.
Georgakopoulos, A. (1992). History, status and future considerations of hydrocarbon exploration in Greece. First Break, 10(11), 413-416.
Georgakopoulos, Α., Papaconstantinou, C, Papaioannou, Ch. (1995). Natural gas storage in the South Kavala Field: geological and seismological characteristics. Petroleum Geoscience, 1(2), 129-133.
Glauser, T.A., Nelson, A.N., Zembower, D.E., Lipsky, J.J., Weinshilboum, R.M. (1993). Evidence for catalysis by human liver thio methyltransferase and thiopurine methyltransferase. Journal of Pharmacology and Experimental Therapeutics, 266(1), 23-32.
Kind, T., Vrana, B., Brack, W., Schurmann, G. (2000). Fractionation and chemical analysis of watercourse SPMD extracts. UFG Center for Environmental Research, Brighton. Internet link: http://www.amdis.net/setac2000-Tobias-Kind.pdf. [Search: 5/2003]
Labunska, I., Santillo, D., Johnston, P., Stringer, R., Stephenson, A. (2000). Heavy metals and organic contaminants in the vicinity of the Teshima Island illegal dumpsite, Kagawa Prefecture, Japan. Greenpeace Research Laboratories, Technical note 02/00.
Haider, N., Karlsson, S. (2002). Loss and transformation products of the aromatic antioxidants in MDPE film under long-term exposure to biotic and abiotic conditions. Journal of Applied Polymer Science, 85(5), 974-988.
O'Malley, MA, Mathias, CG., Priddy, M., Molina, D., Grote, A.A., Halperin, W.E. (1988). Occupational vitiligo due to unsuspected presence of phenolic antioxidant byproducts in commercial bulk rubber. Journal of Occupational Medicine, 30(6), 512-516.
Oros, D.R., David, Ν. (2002). Identification and evaluation of Unidentified Organic Contaminants in the San Francisco Estuary. Regional Monitoring Program for Trace Substances Technical Report. SFEI Contribution 45. San Francisco Estuary Institute, Oakland, CA.
Papa, A.J., Sherman, P.D. (1981). In: Encyclopedia of Chemical Technology, 3rd Ed., 13, 894-941
Peters, M.M, Rivera, M.I., Jones, T.W., Monks, T.J., Lau, S.S. (1996). Glutathione conjugates of tert-butylhydroquinone, a metabolite of the urinary tract tumor promoter 3-tert-butyl-hydroxyanisole, are toxic to kidney and bladder. Cancer Research, 56, 1006-1011.
P.I.C. (Phthalate Information Center) (2003). Internet link: http://www.phthalates.org/. [Search: 5/2003]
Reis, J.C. (1996). Environmental Control in Petroleum Engineering. Gulf Publishing Company, Houston, 274 pp.
Ricking, M., Schwarzbauer, J., Franke, S. (2003). Molecular markers of anthropogenic activity in sediments of the Havel and Spree rivers (Germany). Water research, 37(11), 2607-2617.
Saeger, V.W., Hicks, O., Kaley, R.G., Michael, P.R., Mieure, J.P., Tucker, E.S. (1979). Environmental fate of selected phosphate esters. Environmental Science and Technology, 13, 840-844.
S.F.S. (2001). Internet link: http://www.cas.org/SCIFINDER/SCHOI-AR/index.html. [Search: 5/2003].
Shell Group of Companies (1983). The Petroleum Handbook. Elsevier, AE Amsterdam, The Netherlands, 710ΡΡ-
Sigma-Aldrich (2003). Internet link: http://www.sigmaaldrich.com. [Search: 5/2003].
Spectrum (2003). Internet link: http://www.speclab.com/compound/c103231 .htm. [Search: 5/2003].
Speel, L. (1982). Development of the Oil and Gas Fields Prinos and South Kavala. Oil-Gas European Magazine, 8(2), 6-12.
Strizhakova, Y.A., Levanova, S.V., Sokolov, A.B., Pechatnikov, M.G., Saed, A. (2000). Liquid-phase chlorination of saturated hydrocarbons in the presence of olefins and initiating systems based thereon. Russian Journal of Organic Chemistry (Translation of Zhurnal Organicheskoi Khimi), 36(5), 645-649.
Suwanchaichinda, C, Brattsten, L.B. (2002). Induction of microsomal cytochrome P450s by tire-leachate compounds, habitat components of Aedes albopictus mosquito larvae. Archives of Insect Biochemistry and Physiology, 49, 71-79.
Schwarzbauer, J., Heim, S., Brinker, S., Littke, R. (2002). Occurrence and alteration of organic contaminants in seepage and leakage water from a waste deposit landfill (Germany). Water Research, 36, 2275-2287.
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