IDENTIFICATION OF TREATED-COLOR FRESHWATER CULTURED PEARLS


S. Karampelas
E. Fritsch
S. Sklavounos
T. Soldatos
Résumé

Demand for colored pearls has grown during the last thirty years. Colored pearls are rarer than white ones. Thus treated-color pearls have entered the marketplace and their identification became a challenge for the gemologists. With only the help of visual observation, EDXRF and X-radiography, methods that are used today for pearls identification, it is not always easy to identify them. Previous studies, have established that Raman scattering is useful to detect pigments in cultured freshwater pearls. The present study is based on the measurement of the Raman spectroscopy of 35 natural colored freshwater pearls and 15 treated-color freshwater pearls, covering a wide range of typical colors for this material, with green excitation. All natural- color pearls show the two major Raman resonance features of polacetyenic pigments assigned to C=C stretching-at about 1530(±25) cm'1- and C-C stretching - at about 1130(±10) cm' -, regardless of their specific hue. In this paper it is proposed that the absence of these Raman features prove the artificial origin of pigments in a colored freshwater cultured pearl.

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  • Rubrique
  • Mineralogy-Petrology-Geochemistry-Economic Geology
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Références
Akamatsu, S., Zansheng, T.L., Moses, M.T., and Scarratt, K., 2001. The Current Status of Chinese Freshwater Cultured Pearls, Gems&Gemology, 37(2), 96-113.
Crowningshield, G.R., 1991. Gem Trade Lab Notes: Green-Dyed Natural Pearls, Gems&Gemology, 27(3), 175.
Elen, S., 2001. Spectral reflectance and fluorescence characteristics of natural-color and heattreated "golden" south sea cultured pearls, Gems&Gemology, 37(2), 114-123.
Elen, S., 2002. Note&New Techniques: Update on the identification of treated "golden" south sea cultured pearls, Gems&Gemology, 38(2), 156-159.
Fengming, H., Xinqiang, Y., Mingxing, Y., and Zhonghui, C, 2003. Pearl cultivation in Donggou, Ezhou, Hubei, and cathodoluminescence of cultured pearls, Journal of Gemmology, 28(3), 449-62.
Fryer, C, 1984. Gem Trade Lab Notes: First American Freshwater Cultured Pearls from Tennessee, Gems&Gemology, 20(4), 229-230.
Gauthier, J-P., and Lasnier, B., 1990. La perle noire obtenue par traitment a l'argent, Revue de Gemmologie, A.F.G., 103(1), 3-6.
Goebel, M., and Dirlam, D.M., 1989. Polynesian black pearls, Gems&Gemology, 25(3), 130-148.
Gütmannsbauer, W., and Hanni, H.A., 1994. Structural and chemical investigations on shell and pearls of nacre forming salt- and freshwater bivalve mollusks, Journal of Gemmology, 24(4), 241-252.
Hänni, H.A., 1999. Sur la formation de nacre et de perles, Revue de Gemmologie, A.F.G., 137(1), 30-36.
Hargett, D., 1987. Gem Trade Lab Notes: Black Cultured Pearls, Gems&Gemology, 23(3), 166.
Hoskins, C, and Alexander, V., 1977. Determination of carotenoid concentrations in marine phytoplankton by resonance Raman spectrometry, Analytical Chemistry, 49(6), 695-697'.
Hurwit, K., 1984. Gem Trade Lab Notes: Dyed Cultured Pearls, Gems&Gemology, 20(4), 229.
Jobbins, E.A., and Scarratt, K., 1990. Some aspects of pearl production with particular reference to cultivation at Yangxin, China, Journal of Gemmology, 22 (1), 3-15.
Kane, R., 1990. Freshwater Natural, Gems&Gemology, 26 (3), 223-224.
Karampelas, S., Fritsch, E., Mevellec, J.-Y., Gauthier, J.-P., Sklavounos, S., and Soldâtes, T., 2007. Determination by Raman scattering of the nature of pigments in cultured freshwater pearls from the mollusk Hyriopsis cumingii, Journal of Raman Spectroscopy, 38 (3), pp.217-230.
Kennedy, S.J., 1998. Pearl identification, Australian Gemmologist, 20 (1), 2-19.
Kiefert, L., Moreno, D.M., Arizmendi, E., Hänni, H., and Elen, S., 2004. Cultured pearls from the Gulf of California, Mexico, Gems&Gemology, 40(1), 26-38.
Komatsu, H., 1999. The identification of pearls in Japan. - A status quo summary, Journal of the Gemmological Society of Japan, 20(1-4), 111-119.
Li, L., and Chen, Z., 2001. Cultured pearls and colour-changed cultured pearls: Raman spectra, Journal ofGemmology, 27(8), 449-455.
Matsuda, Y., and Miyoshi, T., 1988. Effects of [gamma]-ray irradiation on colour and fluorescence of pearls, Japanese Journal of Applied Physics, 27(2), 235-239.
Okamoto, H., Saito, S., Tasumi, M.., and Eugster, C, 1984. Resonance Raman spectra and excitation profiles of tetradesmethyl-ß-Carotene, Journal of Raman Spectroscopy, 15(5), 331-335.
Salares, V.R., Young, N.M., Carey, P.R., and Bernstein, H.J., 1977. Excited state (excitation) interactions in polyene aggregates. Resonance Raman and absorption spectroscopic evidence, Journal of Raman Spectroscopy, 6(6), 282-288.
Scarratt, K., Moses, T., and Akamatsu, S., 2000. Characteristics of nuclei in Chinese freshwater cultured pearls, Gems&Gemology, 36(2), 98-109.
Schoeffel, H., 1996. Pearls. From the myths to modern pearl culture, Schoeffel Pearl Culture, Stuttgart, 119pp.
Sweaney, J.L., and Latendresse, J.R., 1984. Freshwater pearls of North America, Gems&Gemology, 20(3), 125-140.
Vock, Α., 1997. Disclosure needed for a healthy industry, Jewellery News Asia, 158(10), 52-54.
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