THE USE OF HEU-TYPE ZEOLITIC TUFF IN SUSTAINABLE AGRICULTURE: EXPERIMENTAL STUDY ON THE DECREASE OF NITRATE LOAD IN VADOSE ZONE LEACHATES


Published: Jul 28, 2016
Keywords:
zeolite agriculture nitrates environmental protection leachates
E. Hatzigiannakis
N. Kantiranis
E. Tziritis
A. Filippidis
G. Arampatzis
E. Tzamos
Abstract

A HEU-type zeolitic tuff of very-high quality (88 wt.% clinoptilolite-heulandite) has been used as an additive to natural soils, aiming to reduce the produced nitrate load in leachates, following a common irrigation scheme. Zeolitic tuff has been added and mixed with agricultural soil in three different proportions (0.2, 0.4 and 0.6%) corresponding to an application of 500, 1000 and 1500 kg per acre. The control soil (without zeolitic tuff) and the three mixtures were exposed in a ten weeks experiment, in which, specific doses of irrigation water enriched in nitrates were added. Results of leachates analyses revealed that the addition of 0.2% zeolitic tuff is not effective and the mixture of soil-zeolitic tuff appears to have similar behaviour with the untreated (reference) soil sample. On the contrary, zeolitic tuff additions by 0.4% and 0.6% showed remarkable results and reduced the nitrate load of leachates by 81 and 86%, respectively. Hence, the impacts from the application of very-high quality HEUtype zeolitic tuff in agricultural soils could be rather positive towards environmental protection and rational farming, an in line with the goals and objectives of the new common agricultural policy imposed by European Union

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  • Special Session: Enviromental Geochemistry
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References
Alexiadis, K., 1967. Physical and chemical soil analysis. Thessaloniki, 78 pp. (in Greek).
Baerlocher, Ch., McCuster, L.B. and Olson, D.H., 2007. Atlas of Zeolite Framework Types.
Amsterdam, Elsevier, 301 pp.
Bower, C.A., Reitemeier, R.F. and Fireman, M., 1952. Exchangeable cation analysis of saline and
alkali soils, Soil Sci. 73, 251-261
Colella, C. and Mumpton, F.A., 2000. Natural Zeolites for the Third Millenium, Napoli, De Frede
Editore, 481 pp.
Council Directive 1991/676/EEC of 12 December 1991 concerning the protection of waters against
pollution caused by nitrates from agricultural sources.
Filippidis, A., 2007. Zeolites of Trigono Municipality of Evros Prefecture in industrial, agricultural,
cattle-raising and environmental technology (in Greek), Proc. Sci. Meet. Development
Perspectives of Northern Evros, Petrota, Evros, Greece, 4 Aug., 89-107.
Filippidis, A., 2008. Treatment and recycling of municipal and industrial waste waters using
Hellenic Natural Zeolite: A Review, Proc. AQUA, 3rd Intern. Conf. Water Sci. & Technology,
Athens, 16-19 Oct., 5 pp.
Filippidis, A., 2009. Management of urban and industrial wastewaters using Hellenic Natural
Zeolite. Review article (in Greek with English summary), Proc. Congr. Integrated Manag.
Water Res. Climatic Change Conditions, Volos, Greece, 27-30 May, II, 829-836.
Filippidis, A., 2010. Environmental, industrial and agricultural applications of Hellenic Natural
Zeolite, Hellenic J. Geosci., 45, 91-100.
Filippidis, A., 2013. Industrial and municipal wastewater treatment by zeolitic tuff, Water Today
V(X), 34-38.
Filippidis, A. and Kantiranis, N., 2007. Experimental neutralization of lake and stream waters from
N. Greece using domestic HEU-type rich natural zeolitic material, Desalination, 213, 47-55.
Filippidis, A. and Tsirambides, A., 2012. Quality characteristics of the Greek zeolites,
environmental, industrial, agricultural and aquacultural uses of Hellenic natural zeolite: A
review (in Greek with English abstract), Scientific Annals, School of Geology, Aristotle
University of Thessaloniki, 101, 125-133.
Filippidis, A., Kantiranis, N., Drakoulis, A. and Vogiatzis, D., 2006. Improvement and protection
of the lake Koronia using natural zeolite (In Greek with English summary), Proc. 2nd Congr.
Aristotle Univ. Environ. Council, Thessaloniki, 1-4 June, 273-279.
Filippidis, A., Apostolidis, N., Paragios, I. and Filippidis, S., 2008a. Zeolites clean up, Industrial
Minerals, 487, 68-71.
Filippidis, A., Apostolidis, N., Paragios, I. and Filippidis, S., 2008b. Safe management of sewage
sludge, produced by treatment of municipal sewage with Hellenic Natural Zeolite, Proc.
AQUA, 3rd Intern. Conf. Water Sci. & Technology, Athens, 16-19 Oct., 5 pp.
Filippidis, A., Tsirambides, A., Kantiranis, N., Tzamos, E., Vogiatzis, D., Papastergios, G.,
Papadopoulos, A. and Filippidis S., 2011a. Purification of wastewater from Sindos industrial
area of Thessaloniki (N. Greece) using Hellenic Natural Zeolite, Proc. 9th Intern. Hydrogeol.
Congr., Kalavrita, Greece, 5-8 Oct., Environ. Earth Sci., Springer, Berlin, Adv. Res. Aquatic
Environ., 2, 435-442.
Filippidis, A., Tsirambides, A., Tzamos, E., Vogiatzis, D., Papastergios, G., Georgiadis, I.,
Papadopoulos, A. and Filippidis, S., 2011b. Purification of wastewater from Thessaloniki
industrial area using Hellenic natural zeolite (in Greek with English abstract), Proc. 21st
Panhellenic Chemistry Congr., Thessaloniki, 9-12 Dec., 8 pp.
Filippidis, A., Kantiranis, N., Vogiatzis, D., Tzamos, E., Papastergios, G. and Filippidis, S., 2012.
Odourless-cohesive zeosewage sludge production and urban wastewater purification by
natural zeolite, Proc. Intern. Conf. Protection & Restoration Environment XI, Thessaloniki,
-6 July, 582-588.
Filippidis, A., Godelitsas, A., Kantiranis, N., Gamaletsos, P., Tzamos, E. and Filippidis, S., 2013.
Neutralization of sludge and purification of wastewater from Sindos industrial area of
Thessaloniki (Greece) using natural zeolite, Bull. Geol. Soc. Greece, 47(2), 920-926.
Filippidis, A., Kantiranis, N., Tziritis, E., Tzamos, E., Vogiatzis, D. and Filippidis, S., 2014. The
use of Hellenic Natural Zeolite (HENAZE) in the purification of Thessaloniki industrial area
wastewaters, Proc. 10th Intern. Hydrogeol. Congr., Thessaloniki, 8-10 Oct., 187-193.
Filippidis, A., Kantiranis, N., Papastergios, G. and Filippidis, S., 2015a. Safe management of
municipal wastewater and sludge by fixation of pollutants in very high quality HEU-type
zeolitic tuff, J. Basic Appl. Res. Intern., 7(1), 1-8.
Filippidis, A., Papastergios, G., Kantiranis, N. and Filippidis, S., 2015b. Neutralization of dyeing
industry wastewater and sludge by fixation of pollutants in very high quality HEU-type
zeolitic tuff, J. Global Ecol. Environ., 2(4), 221-226.
Fu, F. and Wang, Q., 2011. Removal of heavy metal ions from wastewaters: A review, J. Envir.
Manag., 92, 407-418.
Gee, G. and Bauder, J., 1986. Particle Size Analysis. In: Klute, A., eds., Methods of Soil Analyses,
Part 2, 2nd American Society of Agronomy and Soil Science Society of America: Madison,
WI, 9, 383-411.
Godelitsas, A., Charistos, D., Dwyer, J., Tsipis, C., Filippidis, A., Hatzidimitriou, A. and Pavlidou,
E., 1999. Copper (II)-loaded HEU-type zeolite crystals: characterization and evidence of
surface complexation with N,N-diethyldithiocarbamate anions. Microporous & Mesoporous
Materials, 33, 77-87.
Godelitsas, A., Charistos, D., Tsipis, A., Tsipis, C., Filippidis, A., Triantafyllidis, C., Manos, G. and
Siapkas, D., 2001. Characterisation of zeolitic materials with a HEU-type structure modified
by transition metal elements: Definition of acid sites in Nickel-loaded crystals in the light of
experimental and quantum-chemical results, Chemistry-A European Journal, 7, 3705-3721.
Godelitsas, A., Charistos, D., Tsipis, C., Misaelides, P., Filippidis, A. and Schindler, M., 2003.
Heterostructures patterned on aluminosilicate microporous substrates: Crystallisation of
cobalt (III) tris (N,N-diethyl-dithiocarbamato) on the surface of HEU-type zeolite.
Microporous & Mesoporous Materials, 61, 69-77.
Kantiranis, N., Filippidis, A. and Georgakopoulos, A., 2005. Investigation of the uptake ability of
fly ashes produced after lignite combustion, J. of Environmental Management, 76, 119-123.
Kantiranis, N., Filippidis, A., Mouhtaris, T., Paraskevopoulos, K.M., Zorba, T., Squires, C. and
Charistos, D., 2006. EPI-type zeolite synthesis from Greek sulphocalcic fly ashes promoted
by H2O2 solutions, Fuel, 85, 360-366.
Kantiranis, N., Georgakopoulos, A., Filippidis, A. and Drakoulis, A., 2004. Mineralogy and organic
matter content of bottom ash samples from Agios Dimitrios power plant, Greece, Bull. Geol.
Soc. Greece, 36(1), 320-326.
Kantiranis, N., Sikalidis, K., Godelitsas, A., Squires, C., Papastergios, G. and Filippidis, A., 2011.
Extra-framework cation release from heulandite-type rich tuffs on exchange with NH4+, J.
Environ. Management, 92, 1569-1576.
Lichtenberg, E. and Shapiro, L.S., 1997. Agriculture and nitrate concentrations in Maryland
community water system wells, J. Environ. Qual., 26, 145-153.
Malamis, S. and Katsou, E., 2013. A review on zinc and nickel adsorption on natural and modified
zeolite, bentonite and vermiculite: Examination of process parameters, kinetics and
isotherms, J. of Hazar. Mater., 252/253, 428-461.
Masukume, M., Onyango, M.S., Aoyi O. and Otieno, F., 2011. Nitrate removal from groundwater
using modified matural zeolite, Tshwane University of Technology, Department of Chemical
and Matallurgical Engineering, South Africa, Res. Rep., 13 pp.
Mazeikiene, A., Valentukeviciene, M., Rimeika, M., Matuzevicius, A.B. and Dauknys, R., 2008.
Removal of nitrates and ammonium ions from water using natural sorbent zeolite
(clinoptilolite), J. Envir. Eng. Landsc. Manag., 16, 38-44.
Misaelides, P., Godelitsas, A., Filippidis, A., Charistos, D. and Anousis, I., 1995. Thorium and
uranium uptake by natural zeolitic materials, Sci. Total Environment, 173/174, 237-246.
Mitchell, S., Michels, N.L., Kunze, K. and Perez-Ramirez, J., 2012. Visualization of hierarchically
structured zeolite bodies from macro to nano length scales, Nature Chemistry, 4, 825-831.
Perrin, S., Drost, D., Boettinger, J. and Norton, J., 1998. Ammonium-Loaded Clinoptilolite: A Slow-
Release Nitrogen Fertilizer for Sweet Corn, J. of PNutrition, 21(3), 515-530.
Tsitsishvili, G.V., Andronikashvili, T.G., Kirov, G.N. and Filizova, L.D., 1992. Natural Zeolites,
Chichester, England, Ellis Horwood Ltd, 295 pp.
Tzamos, E., Kantiranis, N., Papastergios, G., Vogiatzis, D., Filippidis, A. and Sikalidis, C., 2011.
Ammonium exchange capacity of the Xerovouni zeolitic tuffs, Avdella area, Evros
Prefecture, Greece, Clay Minerals, 46,179-187.
Vogiatzis, D., Kantiranis, N., Filippidis, A., Tzamos, E. and Sikalidis, C., 2012. Hellenic Natural
Zeolite as a replacement of sand in mortar: mineralogy monitoring and evaluation of its
influence on mechanical properties, Geosciences, 2, 298-307.
USDA, 1987. United States Department of Agriculture (USDA), Textural Soil Classification
(Module 3), Soil Mechanics Level -1, Technical report, 48 pp.
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