UPTAKE ABILITY OF ZEOLITIC ROCK FROM SOUTH XEROVOUNI, AVDELLA, EVROS, HELLAS


E. Tzamos
A. Filippidis
N. Kantiranis
C. Sikalidis
A. Tsirambidis
G. Papastergios
D. Vogiatzis
Résumé

Zeolitic rock samples from South Xerovouni contain on average, 57 wt.% HEU type zeolite, 6 wt.% clay minerals, 3 wt.% mica (total of 66 wt.% microporous minerals), 19 wt.% feldspars, 10 wt.% cristobalite and 5 wt.% quartz (total of 34 wt.% non-microporous minerals). Chemically the zeolitic rock consists mainly of 69.9 wt.% SiO2, 13.2 wt.% Al2O3, 1.2 wt.% Fe2O3t, 1.0 wt.% MgO, 3.0 wt.% CaO, 1.5 wt.% Na2O and 2.2 wt.% K2O. The zeolitic rock shows an average ammonia ion exchange capacity of 150 meq/100g. HEU-type zeolite accounts for the most of the uptake ability, while clay minerals and mica contribute to a relative small extent only. The uptake ability of the five zeolitic rock samples showed positive correlations with the content of HEU-type zeolite as well as with the total content of microporous minerals (zeolite + mica + clay minerals). Such materials could be used in a wide range and scale of agricultural, aquacultural, and environmental applications.

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  • Petrology and Mineralogy
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Références
Bain, C. & Smith, L., 1987. Chemical analysis. In: Wilson M. (ed.), A handbook of determinative methods
in clay mineralogy, Glasgow, Blackie, 248-274.
Barrer, R.M., 1978. Zeolite and Clay Minerals as Sorbents and Molecular Sieves, New York, Academic
Press, 499pp.
Bish, D.L. & Ming, D.W., 2001. Natural Zeolites: Occurrence, Properties, Applications. Mineralogical Society
of America , Reviews in Mineralogy and Geochemistry, vol. 45, Washington DC, 654 p.
Breck, D.W., 1974. Zeolite Molecular Sieves, Structure, Chemistry and Use, New York, J. Wiley, 771pp.
Deer, W.A., Howie, R.A. & Zussman, J., 1992. An Introduction to the Rock-Forming Minerals, 2nd edn.
London, Longman, 696pp.
Dyer, A., 1988. An Introduction to Zeolite Molecular Sieves, Chichester, J. Wiley, 149pp.
Filippidis, A. 1993. New find of moissanite in the Metaxades zeolite-bearing volcaniclastic rocks, Thrace
County, Greece. Neues Jahrbuch fur Mineralogie Monatshefte, 11, 521-527.
Filippidis, A. 2008. Treatment and recycling of municipal and industrial waste waters using Hellenic Natural
Zeolite: A Review. AQUA 2008, 3rd Intern. Conf. Water Science and Technology (Athens, 16-
/10), CD-Proceedings, 5p.
Filippidis, A. & Kantiranis, N., 2005. Industrial, agricultural and environmental uses of the natural zeolites
of Thrace. Proc. Sci. Meet. of G.S.G. (Samothraki, 2-4/9), Bull. Geol. Soc. Greece, 37, 90-101
(in Greek with English summary).
Filippidis, A. & Kassoli-Fournaraki, A., 2002. Management of aquatic ecosystems using Greek natural
zeolites. 12th Sem. Environmental Protection (Thessaloniki, 2-5/12), Proceedings, 75-82 (in Greek).
Filippidis, A. & Kassoli-Fournaraki, A., 2000. Environmental uses of natural zeolites from Evros district,
Thrace, Greece. In: Anagnostopoulos A. (Ed.), Proc. 5th Int. Conf. on Environ. Pollution. 149-155,
Thessaloniki, G. Korakidis Press, 1026pp.
Filippidis, A., Godelitsas, A., Charistos, D., Misaelides, P. & Kassoli-Fournaraki, A., 1996. The chemical
behavior of natural zeolites in aqueous environments; interaction between low-silica zeolites and
M NaCl solutions of different pH-values, Applied Clay Science 11, 199-209.
Filippidis, A., Kantiranis, N., Stamatakis, M., Drakoulis, A. & Tzamos, E., 2007. The cation exchange capacity
of the Greek zeolitic rocks. Bull. Geol. Soc. Greece, 40(2), 723-735.
XLIII, No 5 – 2769
Filippidis, A., Apostolidis, N., Paragios, I. and Filippidis, S. 2008. Zeolites clean up. Industrial Minerals,
April, 68-71.
Filippidis, A., Papastergios, G., Apostolidis, N., Paragios, I., Filippidis, S. and Sikalidis, C. 2009. Oderless
and cohesive zeo-sewage sludge produced by Hellenic Natural Zeolite treatment. 3rd AMIREG
Intern. Conf. Assessing the Footprint of Resource Utilization and Hazardous Waste Management
(Athens, 7-9/9), Proceedings, 96-100.
Godelitsas, A., Misaelides, P., Charistos, D., Filippidis, A. & Anousis, I., 1996a. Interaction of HEU-type
zeolite crystals with Thorium aqueous solutions. Chem. Erde 56, 143-156.
Godelitsas, A., Misaelides, P., Filippidis, A., Charistos, D. & Anousis, I., 1996b. Uranium sorption from
aqueous solutions on sodium-form of HEU-type zeolite crystals. J. Radioan. Nucl. Ch. Ar. 208, 393-402.
Gottardi, G. & Galli, E., 1985. Natural zeolites, Berlin, Springer, 409pp.
Haidouti, C., 1997. Inactivation of mercury in contaminated soils using natural zeolites. The Science of
the Total Environment, 208, 105-109.
Holmes, D.A., 1994. Zeolites. In: Industrial Minerals and Rocks (D.D. Carr, ed.), Braun-Brumfield,
Michigan, 1129-1158.
Kantiranis, N., Chrissafis, C., Filippidis, A. & Paraskevopoulos, K., 2006. Thermal distinction of HEUtype
mineral phases contained in Greek zeolite-rich volcaniclastic tuffs. European Journal of Mineralogy,
(4), 509-516.
Kantiranis, N., Stamatakis, M., Filippidis, A. & Squires, C. 2004. The uptake ability of the clinoptilolitic
tuffs of Samos Island, Greece. Bull. Geol. Soc. Greece, 36(1), 89-96.
Kantiranis, N., Filippidis, A., Mouhtaris, Th., Charistos, D., Kassoli-Fournaraki, A. & Tsirambides, A.,
The uptake ability of the Greek natural zeolites, ZEOLITE ’02, 6th Int. Conf. on the Occurrence,
Properties and Utilization of Natural Zeolites, Thessaloniki (June, 3-7 2002), 155-156.
Kassoli-Fournaraki, A., Stamatakis, M., Hall, A., Filippidis, A., Michailidis, K., Tsirambides, A. & Koutles,
Th., 2000. The Ca-rich clinoptilolite deposit of Pentalofos, Thrace, Greece. In: Collela C. &
Mumpton F.A. (Eds.), Natural Zeolites for the Third Millennium, Napoli, De Frede Editore, 193-202.
Katranas, T.K., Vlessidis, A.G., Tsiatouras, V.A., Triantafyllidis, K.S. & Evmiridis, N.P., 2003. Dehydrogenation
of propane over natural clinoptilolite zeolites. Microporous and Mesoporous Materials,
, 189-198.
Koutles, Th., Kassoli-Fournaraki, A., Filippidis, A. & Tsirambides, A. 1995. Geology and geochemistry
of the Eocene zeolitic-bearing volcaniclastic sediments of Metaxades, Thrace, Greece. Estudios Geologicos,
, 19-27.
Marantos, I., Koshiaris, G., Karantasi, S. & Gregoriadis, G., 1989. A study on zeolitic alteration of Tertiary
pyroclastics from Metaxades area, Evros County, Greece. Bull. Geol. Soc. Greece, 23(2), 443-
(in Greek with English abstract).
Mercer, B.W. & Ames, Jr.L.L., 1978. Zeolite Ion Exchange in Radioactive and Municipal Watewater
treatment. In: Sand L.B. & Mumpton F.A. (Eds.), Natural Zeolites, Occurrence, Properties, Uses, Oxford,
Pergamon Press, 451-459.
Merkle, A.B. & Slaughter, M., 1968. Determination and refinement of the structure of heulandite. American
Mineralogist 53, 1120-1138.
Ming, D.W. & Mumpton, F.A., 1995. Natural zeolites ’93: Occurrence, Properties, Use, International
Committee on Natural zeolites, New York, Brockport, 622pp.
Misailidis, P., Godelitsas, A. & Filippidis A., 1994a. Cesium uptake by zeoliferous rocks from Metaxades,
Thrace, Greece. 15th Pan-Hellenic Chemistry Congress, Thessaloniki, Proc. Α, 218-221 (in Greek
with English summary).
XLIII, No 5 – 2770
Misaelides, P., Godelitsas, A. & Filippidis A. 1995a. The use of zeoliferous rocks from Metaxades-Thrace,
Greece, for the removal of caesium from aqueous solutions. Fresenius Environmental Bulletin, 4,
-231.
Misaelides, P., Godelitsas, A., Charistos, V., Ioannou, D. & Charistos, D., 1994b. Heavy metal uptake by
zeoliferous rocks from Metaxades, Thrace, Greece: An exploratory study. Journal of Radioanalytical
and Nuclear Chemistry, Articles, 183, 159-166.
Misaelides, P., Godelitsas, A., Filippidis, A., Charistos, D. & Anousis, I.. 1995b. Thorium and uranium
uptake by natural zeolitic materials. The Science of the Total Environment, 173/174, 237-246.
Misaelides, P., Godelitsas, A., Haristos, D., Noli, F., Filippidis, A. & Sikalidis, C., 1993. Determination
of heavy metal uptake by the sodium form of heulandite using radiochemical techniques. Geol.
Carpath.-Ser. Clays 44, 115-119.
Mumpton, F.A., 1977. Mineralogy and geology of natural zeolites, Mineralogical Society of America, vol.
, Virginia Blacksburg.
Mumpton, F.A., 1978. Natural zeolites: A new industrial mineral commodity. In: Sand B.L. & Mumpton
F.A. (eds.), Natural zeolites: Occurrences, Properties, Uses. New York, Pergamon Press, 3-27.
Mumpton, F.A., 1988. Development and uses for natural zeolites: a critical commentary. In: Kallo D. &
Sherry H.S. (Eds.), Occurrence, Properties and Utilization of Natural Zeolites, Budapest, Akademiai
Kiado, 333-365.
Papadopoulos, A., Fatta, D., Parperis, K., Mentzis, A., Haralambous, K.J. & Loizidou, M., 2004. Nickel
uptake from a wastewater stream produced in a metal finishing industry by combination of ion-exchange
and precipitation methods. Separation and Purification Technology, 39, 181-188.
Pond, G.W. & Mumpton, F.A., 1984. Zeo-Agriculture: Use of Natural Zeolites in Agriculture and Aquaculture,
Colorado, Westview Press, 305pp.
Sikalidis, C.A., 1998. Heavy metals and toxic elements removal from contaminated waters by clay minerals
and zeolite bearing rocks. Fourth Int. Conf. on Environmental Pollution, Thessaloniki, Proceedings,
-110.
Stamatakis, M., Hall, A. & Hein, R., 1996. The zeolite deposits of Greece. Mineralium Deposita 31, 473-481.
Symeopoulos, B., Soupioni, M., Misaelides, P., Godelitsas, A. & Barbayiannis, N. 1996. Neodymium
sorption by clay minerals and zeoliferous rocks. Journal of Radioanalytical and Nuclear Chemistry,
Letters, 212, 421-429.
Tserveni-Gousi, A.S., Yannakopoulos, A.L., Katsaounis, N.K., Filippidis, A. & Kassoli-Fournaraki, A.,
Some interior egg characteristics as influenced by addition of Greek clinoptilolitic rock material
in the hen diet. Archiv fur Getlugelkunde, 61, 291-296.
Tsirambides, A., 1991. Study of zeoliferous volcaniclastic sediments of Metaxades Evros. Mineral Wealth,
, 41-48 (in Greek with English summary).
Tsirambides, A., Filippidis, A. & Kassoli-Fournaraki, A., 1993. Zeolitic alteration of Eocene volcaniclastic
sediments at Metaxades, Thrace, Greece. Applied Clay Science, 7, 509-526.
Tsirambides, A., Kassoli-Fournaraki, A., Filippidis, A. & Soldatos, K., 1989. Preliminary results on clinoptilolite-
containing volcaniclastic sediments from Metaxades, NE Greece. Bull. Geol. Soc. Greece, 23,
-460.
Tsitsishvili, G.V., Andronikashvili, T.G., Kirov, G.N. & Filizova, L.D., 1992. Natural zeolite. New York,
Ellis Horwood, 274pp.
Tsolis-Katagas, P. & Katagas, C., 1989. Zeolites in pre-caldera pyroclastic rocks of the Santorini volcano,
Aegean sea, Greece. Clays and Clay Minerals 37, 497-510.
Tsolis-Katagas, P. & Katagas, C., 1990. Zeolitic diagenesis of Oligocene pyroclastic rocks of the Metax-
(5) XLIII, No 5 – 2771
ades area, Thrace, Greece. Mineralogical Magazine 54, 95-103.
Vlessidis, A.G., Triantafillidis, C.S. & Evmiridis, N.P., 2001. Removal and recovery of p-phenylenediamines
developing coumpounds from photofinishing lab washwater using clinoptilolite tuffs from
Greece. Water Research, 35, 1603-1608.
Yannakopoulos, A., Tserveni-Gousi, A., Kassoli-Fournaraki, A., Tsirambides, A., Michailidis, K., Filippidis,
A. & Lutat, U., 2000. Effects of dietary clinoptilolite-rich tuff on the performance of growingfinishing
pigs. In: Collela C. & Mumpton F.A. (Eds.), Natural Zeolites for the Third Millennium,
Napoli, De Frede, 471-481.
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